Mechanisms of elimination reactions. 30. The contributions of tunneling and heavy-atom motion in the reaction coordinate to deuterium kinetic isotope effects in eliminations from 2-phenylethyl derivatives

1979 ◽  
Vol 101 (25) ◽  
pp. 7594-7599 ◽  
Author(s):  
Sheena B. Kaldor ◽  
William H. Saunders
Keyword(s):  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Reaction Coordinate ◽  
Kinetic Isotope ◽  
Elimination Reactions ◽  
Atom Motion

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations

Measurement of heavy atom kinetic isotope effects by direct mass spectrometric analysis

1979 ◽  
Vol 51 (9) ◽  
pp. 1375-1379 ◽  
Author(s):  
Steven. Rosenberg ◽  
Jack F. Kirsch
Keyword(s):  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Mass Spectrometric ◽  
Mass Spectrometric Analysis ◽  
Spectrometric Analysis ◽  
Kinetic Isotope

ChemInform Abstract: BENZIDINE REARRANGEMENTS. 18. MECHANISM OF THE ACID-CATALYZED DISPROPORTIONATION OF 4,4′-DIIODOHYDRAZOBENZENE. APPLICATION OF HEAVY-ATOM KINETIC ISOTOPE EFFECTS

1983 ◽  
Vol 14 (32) ◽  
Author(s):  
H. J. SHINE ◽  
J. HABDAS ◽  
H. KWART ◽  
M. BRECHBIEL ◽  
A. G. HORGAN ◽  
...  
Keyword(s):  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Acid Catalyzed

Medium effects on heavy-atom kinetic isotope effects. I. Cell model without internal external coordinate interaction

1973 ◽  
Vol 95 (15) ◽  
pp. 4811-4815 ◽  
Author(s):  
Joseph H. Keller ◽  
Peter E. Yankwich
Keyword(s):  
Cell Model ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Medium Effects ◽  
Kinetic Isotope

Heavy-Atom Kinetic Isotope Effects: Primary Interest or Zero Point?

2021 ◽  
Author(s):  
Harvey J. A. Dale ◽  
Andrew G. Leach ◽  
Guy C. Lloyd-Jones
Keyword(s):  
Isotope Effects ◽  
Heavy Atom ◽  
Zero Point ◽  
Kinetic Isotope Effects ◽  
Primary Interest ◽  
Kinetic Isotope
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