Infrared spectra and molecular orbital model for carbon monoxide adsorbed on metals

1969 ◽  
Vol 91 (12) ◽  
pp. 3158-3162 ◽  
Author(s):  
George Blyholder ◽  
Marvin C. Allen
1981 ◽  
Vol 78 ◽  
pp. 927-932 ◽  
Author(s):  
F.J.C.M. Toolenaar ◽  
G.J. van der Poort ◽  
F. Stoop ◽  
V. Ponec

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Maria Maganu ◽  
Filip Chiraleu ◽  
Constantin Draghici ◽  
Gheorghe Mihai

The previous data obtained by 1H-NMR spectroscopy established the existence of an asymmetry of the bond between Pd and p-allylic groups, even in the p-allyl-Pd complexes dimers which are considered usually symmetric dimers. The asymmetry of the bond depends by the substitutes of the allylic group. Other analytical methods were investigated for additional proof of the obtained results. Thus, this paper discusses how this asymmetry would be reflected in the infrared spectra and in the reaction of the complexes with carbon monoxide.


2007 ◽  
Vol 111 (14) ◽  
pp. 5493-5496 ◽  
Author(s):  
Travis E. Jones ◽  
Chen Zuo ◽  
Paul W. Jagodzinski ◽  
Mark E. Eberhart

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