The Salting-out of Molecular Benzoic Acid in Aqueous Salt Solutions at 35°

1937 ◽  
Vol 59 (11) ◽  
pp. 2132-2134 ◽  
Author(s):  
George M. Goeller ◽  
Arthur Osol
Keyword(s):  
Benzoic Acid ◽  
Salt Solutions ◽  
Salting Out ◽  
Aqueous Salt Solutions

scholarly journals Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater

2017 ◽  
Vol 17 (12) ◽  
pp. 7495-7507
Author(s):  
Shuzo Kutsuna
Keyword(s):  
Henry's Law ◽  
Gas Stripping ◽  
Atmospheric Gases ◽  
Salt Solutions ◽  
Salting Out ◽  
Henry’S Law ◽  
Aqueous Salt Solutions ◽  
Water Equilibrium ◽  
Hoff Equation

Abstract. Gas-to-water equilibrium coefficients, KeqS (in M atm−1), of difluoromethane (CH2F2), a hydrofluorocarbon refrigerant (HFC-32), in aqueous salt solutions relevant to seawater were determined over a temperature (T) range from 276 to 313 K and a salinity (S) range up to 51 ‰ by means of an inert-gas stripping method. From the van't Hoff equation, the KeqS value in water, which corresponds to the Henry's law constant (KH), at 298 K was determined to be 0.065 M atm−1. The salinity dependence of KeqS (the salting-out effect), ln(KH∕KeqS), did not obey the Sechenov equation but was proportional to S0. 5. Overall, the KeqS(T) value was expressed by ln(KeqS(T))  =  −49.71 + (77.70 − 0.134  ×  S0. 5)  ×  (100∕T) + 19.14  ×  ln(T∕100). By using this equation in a lower-tropospheric semi-hemisphere (30–90 °S) of the Advanced Global Atmospheric Gases Experiment (AGAGE) 12-box model, we estimated that 1 to 4 % of the atmospheric burden of CH2F2 resided in the ocean mixed layer and that this percentage was at least 4 % in the winter; dissolution of CH2F2 in the ocean may partially influence estimates of CH2F2 emissions from long-term observational data of atmospheric CH2F2 concentrations.

scholarly journals SALTING-OUT PARAMETERS OF GAS SOLUBILITY IN AQUEOUS SALT SOLUTIONS

1970 ◽  
Vol 3 (1) ◽  
pp. 18-24 ◽  
Author(s):  
KAKUSABURO ONDA ◽  
EIZO SADA ◽  
TAKESHI KOBAYASHI ◽  
SHIGEHARU KITO ◽  
KUNIMITSU ITO
Keyword(s):  
Gas Solubility ◽  
Salt Solutions ◽  
Salting Out ◽  
Aqueous Salt Solutions

Activity Coefficients of Benzoic Acid in Some Aqueous Salt Solutions

1956 ◽  
Vol 60 (8) ◽  
pp. 1139-1140 ◽  
Author(s):  
J. N. Sarmousakis ◽  
M. J. D. Low
Keyword(s):  
Benzoic Acid ◽  
Activity Coefficients ◽  
Salt Solutions ◽  
Aqueous Salt Solutions

scholarly journals Experimental determination of Henry's law constants of difluoromethane (HFC-32) and the salting-out effects in aqueous salt solutions relevant to seawater

2017 ◽  
Author(s):  
Shuzo Kutsuna
Keyword(s):  
Henry's Law ◽  
Gas Stripping ◽  
Atmospheric Gases ◽  
Salt Solutions ◽  
Salting Out ◽  
Henry’S Law ◽  
Aqueous Salt Solutions ◽  
Water Equilibrium ◽  
Hoff Equation

Abstract. Gas-to-water equilibrium coefficients, KeqS (in M atm−1) of difluoromethane (CH2F2), a hydrofluorocarbon refrigerant (HFC-32), in aqueous salt solutions relevant to seawater were determined over a temperature (T) range from 276 to 313 K and a salinity (S) range up to 51 ‰ by means of an inert-gas stripping method. From the van't Hoff equation, the KeqS value in water, which corresponds to the Henry's law constant (KH), at 298 K was determined to be 0.064 M atm−1. The salinity dependence of KeqS (the salting-out effect), ln(KH/KeqS), did not obey the Sechenov equation but was represented by an equation involving S and S0.5. Overall, the KeqS(T) value was expressed by ln(KeqS(T)) = −49.7122 + 77.7018 × (100/T) + 19.1379 × ln(T/100) + [−0.2261 + 0.5176 × (T/100)] × S0.5 + [0.0362 − 0.1046 × (T/100)] × S. By using this equation in a lower tropospheric semi-hemisphere (30° S–90° S) of the Advanced Global Atmospheric Gases Experiment (AGAGE) 12-box model, we estimated that 1 to 5 % of the atmospheric burden of CH2F2 resided in the ocean mixed layer and that this percentage was at least 5 % in the winter; dissolution of CH2F2 in the ocean may partially influence estimates of CH2F2 emissions from long-term observational data of atmospheric CH2F2 concentrations.

Salting-In and Salting-Out of Hydrophobic Solutes in Aqueous Salt Solutions

2001 ◽  
Vol 105 (27) ◽  
pp. 6380-6386 ◽  
Author(s):  
Amrit Kalra ◽  
Nihal Tugcu ◽  
Steven M. Cramer ◽  
Shekhar Garde
Keyword(s):  
Salt Solutions ◽  
Salting Out ◽  
Aqueous Salt Solutions ◽  
Hydrophobic Solutes
Sign in / Sign up

Export Citation Format

Share Document