THE TRANSFERENCE NUMBERS OF POTASSIUM CHLORIDE. NEW DETERMINATIONS BY THE HITTORF METHOD AND A COMPARISON WITH RESULTS OBTAINED BY THE MOVING BOUNDARY METHOD

1931 ◽  
Vol 53 (4) ◽  
pp. 1357-1364 ◽  
Author(s):  
Duncan A. MacInnes ◽  
Malcolm. Dole
Keyword(s):  
Potassium Chloride ◽  
Moving Boundary ◽  
Transference Numbers ◽  
Boundary Method

Dynamic simulation of the moving boundary method for measuring transference numbers

2011 ◽  
Vol 513 (1-3) ◽  
pp. 136-138
Author(s):  
Konstantin Zhurov ◽  
Edmund J.F. Dickinson ◽  
Richard G. Compton
Keyword(s):  
Dynamic Simulation ◽  
Moving Boundary ◽  
Transference Numbers ◽  
Boundary Method

Transference numbers by the moving boundary method.

1947 ◽  
Vol 24 (9) ◽  
pp. 454 ◽  
Author(s):  
Paul Bender ◽  
Donald R. Lewis
Keyword(s):  
Moving Boundary ◽  
Transference Numbers ◽  
Boundary Method

Transference numbers and conductance in concentrated copper(II) chloride solutions at 25°C

1983 ◽  
Vol 36 (10) ◽  
pp. 1913 ◽  
Author(s):  
RN Ellis ◽  
RH Stokes ◽  
AC Wright ◽  
M Spiro
Keyword(s):  
Moving Boundary ◽  
Transference Numbers ◽  
Major Constituent ◽  
Concentrated Solutions ◽  
Chloro Complexes ◽  
Chloride Solutions ◽  
Density Measurements ◽  
Boundary Method

Transference numbers in concentrated copper(II) chloride solutions at 25°C are obtained by (i) a modified moving boundary method using other solutions to isolate both electrodes from the CuCl2 solution, and (ii) the e.m.f. method using cells with transference with gaseous chlorine electrodes. Conductance and density measurements are also reported. The transference results support the more recent Russian work against the earlier measurements of Denham; there is no evidence of negative cation constituent transference numbers, and it is concluded that anionic chloro complexes are not a major constituent of the concentrated solutions. In this respect copper(II) chloride differs from the halides of cadmium and zinc.

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