Probing the Electronic Structure of Early Transition-Metal Oxide Clusters:  Polyhedral Cages of (V2O5)n-(n= 2−4) and (M2O5)2-(M = Nb, Ta)

2007 ◽  
Vol 129 (43) ◽  
pp. 13270-13276 ◽  
Author(s):  
Hua-Jin Zhai ◽  
Jens Döbler ◽  
Joachim Sauer ◽  
Lai-Sheng Wang
Author(s):  
Shiqing He ◽  
Qingda Liu ◽  
Xun Wang

Polyoxometalates (POMs) are early transition metal oxide clusters with diverse structures and extensive functions. Due to the excellent redox property and stability, POM clusters can serve as ligands and supports...


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