Theoretical and Experimental Evidence for SN2 Transition States in Oxidative Addition of Methyl Iodide tocis-[M(CO)2I2]-(M = Rh, Ir)

1996 ◽  
Vol 118 (12) ◽  
pp. 3029-3030 ◽  
Author(s):  
Tim R. Griffin ◽  
David B. Cook ◽  
Anthony Haynes ◽  
Jean M. Pearson ◽  
Donato Monti ◽  
...  
Keyword(s):  
Experimental Evidence ◽  
Methyl Iodide ◽  
Transition States ◽  
Oxidative Addition

Oxidative addition capability of triphosphine iron and ruthenium complexes with methyl iodide

2004 ◽  
Vol 689 (4) ◽  
pp. 801-810 ◽  
Author(s):  
Piotr Jaunky ◽  
Helmut W. Schmalle ◽  
Montserrat Alfonso ◽  
Thomas Fox ◽  
Heinz Berke
Keyword(s):  
Methyl Iodide ◽  
Ruthenium Complexes ◽  
Oxidative Addition

Studies in solvolysis. Part VIII. An entropy correlation related to the reaction of various nucleophiles with malachite green

1977 ◽  
Vol 55 (4) ◽  
pp. 686-692 ◽  
Author(s):  
Stephen Harvey Morris ◽  
John Marshall William Scott ◽  
Frederick Steele
Keyword(s):  
Temperature Dependence ◽  
Malachite Green ◽  
Methyl Iodide ◽  
Rate Constants ◽  
Transition States ◽  
Reaction Coordinate ◽  
Similar Correlation ◽  
Displacement Reactions

The entropies of activation related to the reactions of aqueous malachite green with the nucleophiles water, hydroxide, hydrazine, ammonia, hypochlorite, and sulphite have been calculated from the temperature dependence of the rate constants appropriate to these reactions. The entropies of the transition states for these reactions have been characterized and the transition states shown to be 'reactant like'. A similar correlation, based on data for a series of nucleophiles attacking methyl iodide, suggests that the transition states for the SN2 displacement reactions are also 'reactant like' with respect to the attacking nucleophile. A relationship between two distinct parameters each of which is related to the position of transition states along the reaction coordinate is considered.

Oxidative addition of methyl iodide to binuclear complexes [Pt2Me4(.mu.-R2PCH2PR2)2] and the crystal structure of a bridged Pt(IV)-Pt(IV) product, [Me3Pt(.mu.-I)(.mu.-Me2PCH2PMe2)2PtMe3]I

1985 ◽  
Vol 4 (7) ◽  
pp. 1198-1202 ◽  
Author(s):  
Samson S. M. Ling ◽  
Ian R. Jobe ◽  
Ljubica. Manojlovic-Muir ◽  
Kenneth W. Muir ◽  
Richard J. Puddephatt
Keyword(s):  
Crystal Structure ◽  
Methyl Iodide ◽  
Oxidative Addition ◽  
Binuclear Complexes

Solvent effects on the rate of oxidative addition of methyl iodide to di(4-thiocresol)(2,2′-bipyridyl) platinum(II)

2000 ◽  
Vol 599 (2) ◽  
pp. 166-169 ◽  
Author(s):  
Ja’afar K Jawad ◽  
Faisal N.K Al-Obaidy ◽  
Jasim A Hammud ◽  
Fathi Al-Azab
Keyword(s):  
Methyl Iodide ◽  
Solvent Effects ◽  
Oxidative Addition
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