Enhanced Cuprophilic Interactions in Crystalline Catalysts Facilitate the Highly Selective Electroreduction of CO2 to CH4

2021 ◽  
Vol 143 (10) ◽  
pp. 3808-3816
Author(s):  
Lei Zhang ◽  
Xiao-Xin Li ◽  
Zhong-Ling Lang ◽  
Yang Liu ◽  
Jiang Liu ◽  
...  
Keyword(s):  
Cuprophilic Interactions

Nanoclusters of Dicyanocuprate(I) Anions in Aqueous Solutions: Investigating Cuprophilic Interactions

2019 ◽  
Vol 4 (21) ◽  
pp. 6532-6536 ◽  
Author(s):  
Aaron D. Nicholas ◽  
Roger P. Connolly ◽  
Thomas E. Szewczyk ◽  
Howard H. Patterson
Keyword(s):  
Aqueous Solutions ◽  
Cuprophilic Interactions

A solid state highly emissive Cu(i) metallacycle: promotion of cuprophilic interactions at the excited states

2016 ◽  
Vol 52 (76) ◽  
pp. 11370-11373 ◽  
Author(s):  
M. El Sayed Moussa ◽  
S. Evariste ◽  
H.-L. Wong ◽  
L. Le Bras ◽  
C. Roiland ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Excited States ◽  
Cuprophilic Interactions

The supramolecular synthesis of an original thermochromic metal-rich Cu(i) metallacycle (quantum yield 72% at RT) is reported. Important geometrical changes reinforcing cuprophilic interactions are calculated at the excited states.

scholarly journals An unusual coordination polymer containing Cu+ions and featuring possible Cu...Cu `cuprophilic' interactions: poly[di-μ-chlorido-(μ4-3,5-diaminobenzoato-κ4O:O′:N:N′)tricopper(I)(3Cu—Cu)]

2016 ◽  
Vol 72 (1) ◽  
pp. 63-67 ◽  
Author(s):  
Muhammad Kaleem Khosa ◽  
Paul T. Wood ◽  
Simon M. Humphrey ◽  
William T. A. Harrison
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Hydrothermal Conditions ◽  
Complex Crystal Structure ◽  
Metal Metal ◽  
Copper Coordination ◽  
Complex Crystal ◽  
Cu Ions ◽  
Cuprophilic Interactions

Compounds containing copper(I) are of interest for their role in biological processes. The nature of short (< ∼3.2 Å) Cu...Cu contacts within these compounds has been debated, being either described as weakly attractive (bonding) `cuprophilic' interactions, or simply as short metal–metal distances constrained by ligand geometry or largely ionic in nature. The title three-dimensional Cu+-containing coordination polymer, [Cu3(C7H7N2O2)Cl2]n, was formed from thein situreduction of CuCl2in the presence of 3,5-diaminobenzoic acid and KOH under hydrothermal conditions. Its complex crystal structure contains ten distinct CuIatoms, two of which lie on crystallographic inversion centres. The copper coordination geometries include near-linear CuOCl and CuN2, T-shaped CuOCl2and distorted tetrahedral CuOCl3groups. Each CuIatom is also associated with two adjacent metal atoms, with Cu...Cu distances varying from 2.7350 (14) to 3.2142 (13) Å; if all these are regarded as `cuprophilic' interactions, then infinite [\overline{1}01] zigzag chains of CuIatoms occur in the crystal. The structure is consolidated by N—H...Cl hydrogen bonds.

scholarly journals Frontispiece: Cuprophilic Interactions in and between Molecular Entities

2019 ◽  
Vol 25 (38) ◽  
Author(s):  
N. V. Satyachand Harisomayajula ◽  
Serhii Makovetskyi ◽  
Yi‐Chou Tsai
Keyword(s):  
Cuprophilic Interactions

Pressure Control of Cuprophilic Interactions in a Luminescent Mechanochromic Copper Cluster

2015 ◽  
Vol 54 (20) ◽  
pp. 9821-9825 ◽  
Author(s):  
Quentin Benito ◽  
Benoit Baptiste ◽  
Alain Polian ◽  
Ludovic Delbes ◽  
Lucio Martinelli ◽  
...  
Keyword(s):  
Pressure Control ◽  
Copper Cluster ◽  
Cuprophilic Interactions

scholarly journals Cuprophilic interactions in highly luminescent dicopper(i)–NHC–picolyl complexes – fast phosphorescence or TADF?

2016 ◽  
Vol 52 (14) ◽  
pp. 2932-2935 ◽  
Author(s):  
Jörn Nitsch ◽  
Frederick Lacemon ◽  
Andreas Lorbach ◽  
Antonius Eichhorn ◽  
Federico Cisnetti ◽  
...  
Keyword(s):  
Rate Constants ◽  
Highly Efficient ◽  
Radiative Rate ◽  
Cuprophilic Interactions

Cuprophilic interactions can greatly enhance the radiative rate constants via either exceptionally fast phosphorescence or TADF, and thus present a design motif for highly efficient CuI-based emitters.

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