Solubility of carbon monoxide in aqueous mixtures of allyl alcohol, diethylamine, and triethylamine

1988 ◽  
Vol 33 (3) ◽  
pp. 276-278 ◽  
Author(s):  
Mirza M. Taqui Khan ◽  
Shivappa B. Halligudi
Keyword(s):  
Carbon Monoxide ◽  
Allyl Alcohol ◽  
Aqueous Mixtures

scholarly journals The initial stages of the dehydrogenation and isomeric change of allyl alcohol

1926 ◽  
Vol 113 (764) ◽  
pp. 254-258 ◽  
Keyword(s):  
Carbon Monoxide ◽  
Elevated Temperature ◽  
Double Bond ◽  
Allyl Alcohol ◽  
Catalytic Decomposition ◽  
Unsaturated Alcohol ◽  
Reaction Products ◽  
Brass Tube ◽  
Saturated Aldehyde ◽  
Lower Temperature

The catalytic decomposition of allyl alcohol has been studied by Ipatiev, who passed the vapour through a brass tube filled with brass filings maintained at 600° C. He found hydrogen and acrolein, some propylene and carbon monoxide, with a little divinyl in the reaction products, showing that under these conditions of elevated temperature very little hydrogenation of the double bond of the unsaturated alcohol takes place. Sabatier and Senderensf used reduced copper as catalyst at temperatures varying from 180-300° C. They found that a yield of over 50 per cent, of propionaldehyde could be obtained and only a little acrolein and hydrogen. The lower temperature seems to favour the production of the saturated aldehyde. The observations of Moureu and Boismenu have shown that acrolein is very appreciably hydrogenated by copper at temperatures between 110 and 250° C. At 300° C. the destruction of the acrolein is very rapid. It is evident, therefore, that there are two reactions to be followed in the initial stages of the dehydrogenation of allyl alcohol by copper CH 2 ═ CH . CH 2 OH— ↗CH 3 . CH 2 . CHO ↘ CH 2 = CH. CHO + H 2 A detailed study was made of these two reactions to attempt to throw light on the state of the adsorbed molecules, and to consider in detail the mechanism of the two reactions and the connection between them.

Solubility of carbon monoxide in aqueous mixtures of methanol, acetic acid, ethanol and propionic acid

1985 ◽  
Vol 30 (4) ◽  
pp. 400-403 ◽  
Author(s):  
Subodh B. Dake ◽  
Raghunath V. Chaudhari
Keyword(s):  
Carbon Monoxide ◽  
Acetic Acid ◽  
Propionic Acid ◽  
Aqueous Mixtures

Allyl alcohol as masking agent in determination of copper(I) and copper(II) in aqueous mixtures

1982 ◽  
Vol 54 (13) ◽  
pp. 2307-2310 ◽  
Author(s):  
Gerardo. Ulibarri ◽  
Tetsuya. Ogura ◽  
Jau Hwan. Tzeng ◽  
Nelson. Scott ◽  
Quintus. Fernando
Keyword(s):  
Allyl Alcohol ◽  
Aqueous Mixtures ◽  
Determination Of Copper

Hydroformylation of allyl alcohol catalyzed by Ru(III)-EDTA complex using carbon monoxide and water as a source of hydrogen

1988 ◽  
Vol 48 (1) ◽  
pp. 7-9 ◽  
Author(s):  
M.M.Taqui Khan ◽  
S.B. Halligudi ◽  
S.H.R. Abdi
Keyword(s):  
Carbon Monoxide ◽  
Allyl Alcohol ◽  
Edta Complex

scholarly journals DIRECT SYNTHESIS OF 1,4-BUTANEDIOL FROM ALLYL ALCOHOL USING CARBON MONOXIDE AND WATER IN THE PRESENCE OF Rh6(CO)16-PROPANEDIAMINE SYSTEM

1983 ◽  
Vol 12 (9) ◽  
pp. 1465-1466 ◽  
Author(s):  
Kiyotomi Kaneda ◽  
Toshinobu Imanaka ◽  
Shiichiro Teranishi
Keyword(s):  
Carbon Monoxide ◽  
Allyl Alcohol ◽  
Direct Synthesis

Carbon monoxide poisoning

2000 ◽  
Vol 12 (4) ◽  
pp. 354-357
Author(s):  
David R Smart ◽  
Paul D Mark
Keyword(s):  
Carbon Monoxide ◽  
Carbon Monoxide Poisoning
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