Vapor–Liquid Equilibrium, Excess Molar Enthalpies, and Excess Molar Volumes of Binary Mixtures Containing Methyl Isobutyl Ketone (MIBK) and 2-Butanol, tert-Pentanol, or 2-Ethyl-1-hexanol

2012 ◽  
Vol 57 (11) ◽  
pp. 3092-3101 ◽  
Author(s):  
Helena Laavi ◽  
Anna Zaitseva ◽  
Juha-Pekka Pokki ◽  
Petri Uusi-Kyyny ◽  
Younghun Kim ◽  
...  
Keyword(s):  
Binary Mixtures ◽  
Methyl Isobutyl Ketone ◽  
Excess Molar Volumes ◽  
Excess Molar Enthalpies ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Molar Volumes ◽  
Vapor Liquid

Vapor-Liquid Equilibrium for Binary Systems of Methyl Ethyl Ketone and Methyl Isobutyl Ketone

2012 ◽  
Vol 550-553 ◽  
pp. 2616-2620
Author(s):  
Xiao Li ◽  
Yun Ren Qiu
Keyword(s):  
Temperature Variation ◽  
Methyl Isobutyl Ketone ◽  
Methyl Ethyl ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Equilibrium Data ◽  
The Mean ◽  
Vapor Liquid

Atmospheric vapor-liquid equilibrium data of methyl ethyl ketone (MEK) - methyl isobutyl ketone (MIBK) were measured using an improved Rose still and were used to recover the parameters of NRTL and UNIQUAC models. The results show that the simulated results agree well with the experimental data. The mean temperature variation is 0.14 °C and the mean mole fraction variation is 0.0023 using UNIQUAC model while the mean temperature variation is 0.17 °C and the mean mole fraction variation is 0.0025 using NRTL model. Both models can be used to calculate the atmospheric vapor-liquid equilibrium data of MEK - MIBK.

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