STUDY OF THE PROCESS OF HYDRATION OF MESITYL OXIDE IN THE PRESENCE OF NANOCATALYZERS

The process of mesityl oxide hydrogenation in the presence of a nickel catalyst prepared by impregnating a support with an aqueous solution of the corresponding salt in a displacement reactor in a gas-liquid-solid catalyst system has been studied. It has been established that the use of the catalyst used in the work makes it possible to selectively obtain methyl isobutyl ketone with complete conversion of mesityl oxide in the temperature range 70-100 ºС.

Mesityl Oxide Reduction by Using Acid-Modified Phonolite Supported NiW, NiMo, and CoMo Catalysts

Mesityl oxide is standardly used to produce methyl iso butyl ketone but it can be also used to produce other useful compounds. Three catalysts were used for the reaction of the mesityl oxide reduction. They were NiW, NiMo, and CoMo supported on phonolite modified by HCl (metals/Ph-HCl). The fresh catalysts were characterized by XRD, XRF, BET surface, Hg porosimetry, SEM, H2-TPR, NH3-TPD, CO2-TPD. The materials were directly used, previously reduced in H2 or sulfided for the mesityl oxide reduction under H2 atmosphere. The reaction was performed in an autoclave at T = 375 °C, p = 50 bar (H2), and TOS = 1.5 h. The products were analyzed by GC/MS, GC/FID-TCD, ATR. The main products were methyl isobutyl ketone, 2-methyl pentane, and 2-methyl-2-pentene. Sulfided metal catalysts were the most active in the methyl isobutyl ketone, where the NiWSx/Ph-HCl catalyst showed the highest activity. For the non-previously-activated and hydrogen activated catalysts the most active catalyst was the NiMo/Ph-HCl for the production of methyl isobutyl ketone. The catalyst CoMo/Ph-HCl activated in hydrogen was the most active for the production of 2-methyl pentane compared to the other two hydrogen-activated materials.

Removal of Cobalt (II) from Waters Contaminated by the Biomass of Eichhornia crassipes

Due to the increase in contamination of aquatic niches by different heavy metals, different technologies have been studied to eliminate these pollutants from contaminated aquatic sources. So the objective of this work was to determine the removal of cobalt (II) in aqueous solution by the biomass of the aquatic lily or water hyacinth (Eichhornia crassipes) which, is one of the main weeds present in fresh water, due to its rapid reproduction, growth, and high competitiveness, by the colorimetric method of the methyl isobutyl ketone. The removal was evaluated at different pHs (4.0–8.0) for 28 h. The effect of temperature in the range from 20 °C to 50 °C and the removal at different initial concentrations of cobalt (II) of 100 to 500 mg/L was also studied. The highest bioadsorption (100 mg/L) was at 28 h, at pH 5.0 and 28 °C, with a removal capacity of 73.1%, which is like some reports in the literature. Regarding the temperature, the highest removal was at 50 °C, at 28 h, with a removal of 89%. At the metal and biomass concentrations analyzed, its removal was 82% with 400–500 mg/L, and 100% with 5 g of natural biomass at 20 h. In addition, this completely removes the metal in situ (100 mg/L in contaminated water, at 7 days of incubation, with 10 g of natural biomass in 100 mL). So, the natural biomass can be used to remove it from industrial wastewater, even if in vivo, only eliminate 17.3% in 4 weeks.