Crown ether mediated transport of guanidinium thiocyanate through a bulk liquid membrane and the correlation with the complex stability constants

1986 ◽  
Vol 51 (25) ◽  
pp. 4891-4898 ◽  
Author(s):  
Theodorus B. Stolwijk ◽  
Peter D. J. Grootenhuis ◽  
Peter D. Van der Wal ◽  
Ernst J. R. Sudholter ◽  
David N. Reinhoudt ◽  
...  
Keyword(s):  
Crown Ether ◽  
Stability Constants ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
Complex Stability ◽  
Bulk Liquid Membrane ◽  
Guanidinium Thiocyanate ◽  
Complex Stability Constants

Changes in the Humic Acid–Metal Complexation Characteristics Depending on Humification Degree / Humīnskābju – Metālu Kompleksveidošanās Rakstura Izmaiņas Atkarībā No Humifikācijas Pakāpes

2012 ◽  
Vol 51 (3) ◽  
pp. 228-237
Author(s):  
D. Dudare ◽  
M. Klavins
Keyword(s):  
Humic Acid ◽  
Stability Constants ◽  
Humic Acids ◽  
Complex Stability ◽  
Peat Layer ◽  
Raised Bog ◽  
Complexing Capacity ◽  
Humification Degree ◽  
Complexation Process ◽  
Complex Stability Constants

The aim of this study is to determine the Cu(II) complexing capacity and stability constants of Cu(II) complexes of humic acids isolated from two well-characterized raised bog peat profiles in respect to the basic properties and humification characteristics of the studied peats and their humic acids. The complex stability constants significantly change within the studied bog profiles and are well correlated with the age and decomposition degree of the peat layer from which the humic acids have been isolated. Among factors that influence this complexation process, molecular mass and ability to form micellar structures (supramolecules) of humic substances are of key importance.

scholarly journals Liquid-liquid extraction and facilitated membrane transport of Pb2+ using a lipophilic acridono-crown ether as carrier

2020 ◽  
Vol 99 (1-2) ◽  
pp. 117-129
Author(s):  
Ádám Golcs ◽  
László Bezúr ◽  
Péter Huszthy ◽  
Tünde Tóth
Keyword(s):  
Membrane Transport ◽  
Metal Ion ◽  
Liquid Membrane ◽  
Competitive Inhibition ◽  
Liquid Extraction ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Liquid Liquid Extraction ◽  
Component Systems ◽  
Source Phase

AbstractStudies on liquid-liquid extraction and bulk liquid membrane (BLM) technique-based metal ion separation by a previously published Pb2+-selective acridono-18-crown-6 ether selector molecule were performed. The effects of the stirring speed, the quality of apolar organic membrane, the counterions of Pb2+, the pH of the aqueous phase, the concentration of the source phase, the concentration of the carrier in the BLM and the temperature on the Pb2+-separation were investigated. Moreover, the effects of the competitive inhibition due to the presence of Ag+, Ca2+, Co2+, Cu2+, K+, Mg2+, Na+ and Zn2+ as competing ions in a multicomponent aqueous source phase of different ion-concentrations were also studied. After a proper dilution of the multicomponent aqueous source phase, excellent Pb2+-selectivity was achieved without a significant reduction in the efficiency compared to the liquid membrane transport of single-component systems. Based on the BLM-cell studies the applied selector molecule proved to be suitable for the development of liquid membrane-based Pb2+-selective separation methods, which can be greatly aided by the analysis of the effects on the separation and by the optimization of the parameters of the process discussed here.

Kinetic study of chromium(VI) facilitated transport through a bulk liquid membrane using tri-n-butyl phosphate as carrier

2009 ◽  
Vol 150 (1) ◽  
pp. 83-89 ◽  
Author(s):  
Weidong Zhang ◽  
Junteng Liu ◽  
Zhongqi Ren ◽  
Shuguang Wang ◽  
Changshun Du ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Liquid Membrane ◽  
Facilitated Transport ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Chromium Vi

Transport of carbohydrates across a bulk liquid membrane with substituted calyx[8]arenes and phosphoryl-containing podand

1998 ◽  
Vol 47 (1) ◽  
pp. 177-178 ◽  
Author(s):  
I. V. Lyutikova ◽  
I. V. Pletnev ◽  
I. G. Matveeva ◽  
I. I. Torocheshnikova
Keyword(s):  
Liquid Membrane ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane
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