Facile and selective chlorination-cleavage of some cyclanones and cyclanols with the carbon tetrachloride-potassium hydroxide-tert-butyl alcohol reagent. In situ conversion of estrones and estradiols into dichlorodoisynolic acids

1978 ◽  
Vol 43 (10) ◽  
pp. 1985-1990 ◽  
Author(s):  
Cal Y. Meyers ◽  
Vera M. Kolb
Keyword(s):  
Carbon Tetrachloride ◽  
Potassium Hydroxide ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Selective Chlorination ◽  
Tert Butyl Alcohol

Association and hydration of alcohols in low-dielectric solvents. II. tert-Butyl alcohol and cyclohexanol

1976 ◽  
Vol 54 (24) ◽  
pp. 3929-3943
Author(s):  
Jitka Kirchnerová ◽  
Genille C. B. Cave
Keyword(s):  
Carbon Tetrachloride ◽  
Formation Constants ◽  
Butyl Alcohol ◽  
Mathematical Treatment ◽  
Tert Butyl ◽  
Low Dielectric ◽  
Tert Butyl Alcohol

Formulae and thermodynamic formation constants of the aggregates of tert-butyl alcohol and of cyclohexanol and their hydrates in six low-dielectric solvents have been deduced by using an iterative mathematical treatment of distribution and isopiestic data. The solvents were cyclohexane, carbon tetrachloride, p-xylene, benzene, chlorobenzene, and o-dichlorobenzene. These results and those previously obtained for n-butanol in the same six solvents are discussed in a qualitative way.

Kinetics and Modeling Study on Etherification of Glycerol Using Isobutylene by in Situ Production from tert-Butyl Alcohol

2015 ◽  
Vol 54 (19) ◽  
pp. 5213-5219 ◽  
Author(s):  
Jasvinder Singh ◽  
Jitendra Kumar ◽  
M. S. Negi ◽  
Dinesh Bangwal ◽  
Savita Kaul ◽  
...  
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
In Situ Production ◽  
Modeling Study

Transition Metal-Free Stereoselective α-Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert-Butyl Alcohol/Dimethyl Sulfoxide

2012 ◽  
Vol 354 (9) ◽  
pp. 1813-1818 ◽  
Author(s):  
Boris A. Trofimov ◽  
Elena Yu. Schmidt ◽  
Nadezhda V. Zorina ◽  
Elena V. Ivanova ◽  
Igor' A. Ushakov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Dimethyl Sulfoxide ◽  
Potassium Hydroxide ◽  
Catalytic Triad ◽  
Butyl Alcohol ◽  
Cyclic Ketones ◽  
Metal Free ◽  
Tert Butyl ◽  
Tert Butyl Alcohol
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