Dimethyl sulfoxide-trifluoroacetic anhydride. New reagent for oxidation of alcohols to carbonyls

1976 ◽  
Vol 41 (6) ◽  
pp. 957-962 ◽  
Author(s):  
Kanji. Omura ◽  
Ashok K. Sharma ◽  
Daniel. Swern
Keyword(s):  
Dimethyl Sulfoxide ◽  
Trifluoroacetic Anhydride ◽  
Oxidation Of Alcohols

ChemInform Abstract: DIMETHYL SULFOXIDE-TRIFLUOROACETIC ANHYDRIDE. NEW REAGENT FOR OXIDATION OF ALCOHOLS TO CARBONYLS

1976 ◽  
Vol 7 (26) ◽  
pp. no-no
Author(s):  
K. OMURA ◽  
A. K. SHARMA ◽  
D. SWERN
Keyword(s):  
Dimethyl Sulfoxide ◽  
Trifluoroacetic Anhydride ◽  
Oxidation Of Alcohols

Further Studies on the Oxidation of Alcohols to Carbonyl Compounds by Dimethyl Sulfoxide/Trifluoroacetic Anhydride

Synthesis ◽  
1978 ◽  
Vol 1978 (04) ◽  
pp. 297-299 ◽  
Author(s):  
S. L. HUANG ◽  
Kanji OMURA ◽  
Daniel SWERN
Keyword(s):  
Dimethyl Sulfoxide ◽  
Carbonyl Compounds ◽  
Trifluoroacetic Anhydride ◽  
Oxidation Of Alcohols

Oxidation of Alcohols by Dimethyl Sulfoxide and Oxalyl Chloride (Swern Oxidation)

2008 ◽  
pp. 1
Author(s):  
J. L. García Ruano ◽  
M. B. Cid ◽  
A. M. Martín-Castro ◽  
J. Alemán
Keyword(s):  
Dimethyl Sulfoxide ◽  
Oxalyl Chloride ◽  
Oxidation Of Alcohols ◽  
Swern Oxidation

Oxidation of Alcohols by Dimethyl Sulfoxide and Dicyclohexylcarbodiimide

2008 ◽  
pp. 1
Author(s):  
J. L. García Ruano ◽  
M. B. Cid ◽  
A. M. Martín-Castro ◽  
J. Alemán
Keyword(s):  
Dimethyl Sulfoxide ◽  
Oxidation Of Alcohols

N,N-Dialkyl-N′-Chlorosulfonyl Chloroformamidines in Heterocyclic Synthesis. Part XIII. Cleavage and Rearrangement Reactions of Pyrazolo[1,5-b][1,2,4,6]thiatriazine 1,1-Dioxides

2016 ◽  
Vol 69 (1) ◽  
pp. 61 ◽  
Author(s):  
Rebecca E. Norman ◽  
Michael V. Perkins ◽  
Andris J. Liepa ◽  
Craig L. Francis
Keyword(s):  
Ethyl Acetate ◽  
Dimethyl Sulfoxide ◽  
Trifluoroacetic Acid ◽  
Sulfonic Acid ◽  
Trifluoroacetic Anhydride ◽  
Ring Cleavage ◽  
Thermal Rearrangement ◽  
Heterocyclic Synthesis ◽  
Similar Treatment ◽  
Catalytic Hydrogenolysis

Treatment of pyrazolo[1,5-b][1,2,4,6]thiatriazines 1 with the Vilsmeier–Haack reagent afforded pyrazolo[1,5-a][1,3,5]triazines 5. Reaction of compounds 1 with trifluoroacetic anhydride, dimethyl sulfoxide, and triethylamine afforded 5-dimethylsulfanylidene derivatives 8. The guanidino-pyrazole-sulfonic acid 9 was produced from treatment of compounds 1 with trifluoroacetic acid under anhydrous conditions. Similar treatment in the presence of water afforded the desulfonated pyrazolo-guanidine 6. Reactions of 6 with one-carbon electrophiles provided various 4-substituted pyrazolo[1,5-a][1,3,5]triazines 5. Attempted catalytic hydrogenolysis of N7-benzyl pyrazolo[1,5-b][1,2,4,6]thiatriazines 2 in alcohols led to sulfamates 12 from thiatriazine ring cleavage. Ethyl acetate or tert-butanol as solvent allowed successful debenzylation to provide compounds 1. Aminolysis of compounds 2 gave sulfamides 13. Thermal rearrangement of compounds 2 afforded 6-benzyl-pyrazolo[3,4-e][1,2,4]thiadiazines 14.

scholarly journals Development of a Metal-Free Oxidation of Alcohols with Dimethyl Sulfoxide (DMSO) Activated by Tosyl Chloride

2014 ◽  
Vol 44 (19) ◽  
pp. 2818-2825 ◽  
Author(s):  
Fariba Saadati ◽  
Kobra Yousefi
Keyword(s):  
Dimethyl Sulfoxide ◽  
Metal Free ◽  
Tosyl Chloride ◽  
Oxidation Of Alcohols ◽  
Free Oxidation

Synthetic Methods and Reactions; 771. Dimethyl Sulfoxide/Chlorosulfonyl Isocyanate: An Extremely Mild Reagent for Oxidation of Alcohols to Carbonyl Compounds

Synthesis ◽  
1980 ◽  
Vol 1980 (02) ◽  
pp. 141-142 ◽  
Author(s):  
George A. Olah ◽  
Yashwant D. Vankar ◽  
Massoud Arvanaghi
Keyword(s):  
Dimethyl Sulfoxide ◽  
Carbonyl Compounds ◽  
Synthetic Methods ◽  
Chlorosulfonyl Isocyanate ◽  
Oxidation Of Alcohols

ChemInform Abstract: Oxidation of Alcohols by Activated Dimethyl Sulfoxide and Related Reactions: an Update

ChemInform ◽  
2010 ◽  
Vol 22 (12) ◽  
pp. no-no
Author(s):  
T. T. TIDWELL
Keyword(s):  
Dimethyl Sulfoxide ◽  
Oxidation Of Alcohols

Oxidation of vicinal diols to .alpha.-dicarbonyl compounds by trifluoroacetic anhydride-activated dimethyl sulfoxide

1987 ◽  
Vol 52 (22) ◽  
pp. 4851-4855 ◽  
Author(s):  
Catherine M. Amon ◽  
Martin G. Banwell ◽  
G. Lance Gravatt
Keyword(s):  
Dimethyl Sulfoxide ◽  
Trifluoroacetic Anhydride ◽  
Dicarbonyl Compounds ◽  
Vicinal Diols
Sign in / Sign up

Export Citation Format

Share Document