Base-catalyzed intermolecular condensation of .alpha.,.beta.-unsaturated ketones. Condensation of benzaldehyde with 2-butanone to diketones 3,5-diphenyl-2-methyl-4-propionylcyclohexan-1-one and 4-(2-benzalpropionyl)-3,5-diphenyl-2-methylcyclohexan-1-one

Arnold T. Nielsen; Henry Dubin; Kerry Hise

doi:10.1021/jo01286a028

Base-catalyzed intermolecular condensation of .alpha.,.beta.-unsaturated ketones. Condensation of benzaldehyde with 2-butanone to diketones 3,5-diphenyl-2-methyl-4-propionylcyclohexan-1-one and 4-(2-benzalpropionyl)-3,5-diphenyl-2-methylcyclohexan-1-one

The Journal of Organic Chemistry ◽

10.1021/jo01286a028 ◽

1967 ◽

Vol 32 (11) ◽

pp. 3407-3411 ◽

Cited By ~ 5

Author(s):

Arnold T. Nielsen ◽

Henry Dubin ◽

Kerry Hise

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Tandem conjugate addition. Aldol reactions employing 9-(phenylseleno)-9-borabicyclononane: a novel method for effecting formal aldol condensations at the .alpha.-carbon of .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00205a048 ◽

1985 ◽

Vol 50 (5) ◽

pp. 730-732 ◽

Cited By ~ 30

Author(s):

William R. Leonard ◽

Tom Livinghouse

Keyword(s):

Conjugate Addition ◽

Aldol Reactions ◽

Unsaturated Ketones ◽

Novel Method ◽

Alpha Beta ◽

Alpha Carbon

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Mechanism of photochemical alcohol addition to .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00991a078 ◽

1967 ◽

Vol 89 (15) ◽

pp. 3949-3950 ◽

Cited By ~ 17

Author(s):

B. J. Ramey ◽

Pete D. Gardner

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Nickel-catalyzed conjugate addition of alkynyl groups to .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo01303a024 ◽

1980 ◽

Vol 45 (15) ◽

pp. 3053-3061 ◽

Cited By ~ 81

Author(s):

Jeffrey Schwartz ◽

Denise B. Carr ◽

Robert T. Hansen ◽

Fabian M. Dayrit

Keyword(s):

Conjugate Addition ◽

Unsaturated Ketones ◽

Alpha Beta

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Acid-catalyzed and base-catalyzed hydration of .beta.-oxy-.alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00790a029 ◽

1973 ◽

Vol 95 (9) ◽

pp. 2905-2911 ◽

Cited By ~ 14

Author(s):

L. R. Fedor ◽

N. C. De ◽

S. K. Gurwara

Keyword(s):

Unsaturated Ketones ◽

Acid Catalyzed ◽

Alpha Beta

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Stereochemistry and mechanism of the reaction of LiCuMe2 with .beta.-cyclopropyl .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00509a033 ◽

1979 ◽

Vol 101 (15) ◽

pp. 4236-4244 ◽

Cited By ~ 42

Author(s):

Charles P. Casey ◽

Mark C. Cesa

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta ◽

Mechanism Of The Reaction

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Effect of .beta.-substituents on the reactions of amines with .alpha.-bromo-.alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo01282a014 ◽

1967 ◽

Vol 32 (7) ◽

pp. 2145-2148 ◽

Cited By ~ 6

Author(s):

Norman H. Cromwell ◽

Marvin C. McMaster

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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A comparison of the reactions of [(phenylthio)(trimethylsilyl)methyl]lithium with .alpha.,.beta.-unsaturated ketones and those of other acyl anion equivalents containing sulfur

The Journal of Organic Chemistry ◽

10.1021/jo00371a014 ◽

1986 ◽

Vol 51 (21) ◽

pp. 3983-3992 ◽

Cited By ~ 43

Author(s):

David J. Ager ◽

Michael B. East

Keyword(s):

Unsaturated Ketones ◽

Acyl Anion ◽

Alpha Beta

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Equilibriums between .alpha.,.beta.- and .beta.,.gamma.-unsaturated ketones in six-membered rings fused .beta.-.gamma. to five-, six-, and seven-membered rings

The Journal of Organic Chemistry ◽

10.1021/jo00880a005 ◽

1976 ◽

Vol 41 (18) ◽

pp. 2959-2962 ◽

Cited By ~ 17

Author(s):

James C. Aumiller ◽

John A. Whittle

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Palladium-catalyzed decarboxylation-dehydrogenation of allyl .beta.-oxo carboxylates and allyl enol carbonates as a novel synthetic method for .alpha.-substituted .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00385a075 ◽

1982 ◽

Vol 104 (21) ◽

pp. 5844-5846 ◽

Cited By ~ 82

Author(s):

Isao Shimizu ◽

Jiro Tsuji

Keyword(s):

Synthetic Method ◽

Unsaturated Ketones ◽

Palladium Catalyzed ◽

Alpha Beta

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Palladium-catalyzed asymmetric 1,4-disilylation of .alpha.,.beta.-unsaturated ketones: catalytic asymmetric synthesis of .beta.-hydroxy ketones

Journal of the American Chemical Society ◽

10.1021/ja00224a057 ◽

1988 ◽

Vol 110 (16) ◽

pp. 5579-5581 ◽

Cited By ~ 92

Author(s):

Tamio. Hayashi ◽

Yonetatsu. Matsumoto ◽

Yoshihiko. Ito

Keyword(s):

Asymmetric Synthesis ◽

Unsaturated Ketones ◽

Catalytic Asymmetric Synthesis ◽

Hydroxy Ketones ◽

Palladium Catalyzed ◽

Alpha Beta ◽

Catalytic Asymmetric

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