scholarly journals Two Rare-Class Tricyclic Diterpenes with Antitubercular Activity from the Caribbean SpongeSvenzea flava. Application of Vibrational Circular Dichroism Spectroscopy for Determining Absolute Configuration

2013 ◽  
Vol 78 (22) ◽  
pp. 11294-11301 ◽  
Author(s):  
Edward Avilés ◽  
Abimael D. Rodríguez ◽  
Jan Vicente
Keyword(s):  
Circular Dichroism ◽  
Absolute Configuration ◽  
Antitubercular Activity ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Rare Class ◽  
The Caribbean ◽  
Circular Dichroïsm

Structure and Absolute Configuration of Nyasol and Hinokiresinol via Synthesis and Vibrational Circular Dichroism Spectroscopy

2005 ◽  
Vol 68 (11) ◽  
pp. 1603-1609 ◽  
Author(s):  
Peter R. Lassen ◽  
Dorthe Mondrup Skytte ◽  
Lars Hemmingsen ◽  
Simon Feldbæk Nielsen ◽  
Teresa B. Freedman ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Absolute Configuration ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm

scholarly journals Absolute configuration of the antimalarial erythro-mefloquine – vibrational circular dichroism and X-ray diffraction studies of mefloquine and its thiourea derivative

RSC Advances ◽  
2016 ◽  
Vol 6 (85) ◽  
pp. 81461-81465 ◽  
Author(s):  
M. Kohout ◽  
J. Vandenbussche ◽  
A. Roller ◽  
J. Tůma ◽  
J. Bogaerts ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Absolute Configuration ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
X Ray Diffraction ◽  
Thiourea Derivative ◽  
X Ray ◽  
The Absolute ◽  
Circular Dichroïsm

The long-standing discussion of the absolute configuration of erythro-mefloquine is revisited, showcasing the strength of a combination of experimental and calculated vibrational circular dichroism spectroscopy.

scholarly journals VCD Determination of the Absolute Configuration of Stypotriol

2009 ◽  
Vol 4 (8) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Aurelio San-Martín ◽  
Juana Rovirosa ◽  
Pedro Joseph-Nathan
Keyword(s):  
Circular Dichroism ◽  
Natural Product ◽  
Absolute Configuration ◽  
Circular Dichroism Spectroscopy ◽  
Vibrational Circular Dichroism ◽  
Stypopodium Zonale ◽  
The Absolute ◽  
Circular Dichroïsm

The absolute configuration of the pentacyclic ichthyotoxin stypotriol, a constituent of Stypopodium zonale, was deduced to be 3S,5R,8R,9R,10S,13S,14S-(-)-1 by vibrational circular dichroism spectroscopy of the derived triacetate 2 in comparison to DFT B3LYP/DGDZVP calculations. Compound 2, C33H46O7 having 300 electrons, is the largest natural product successfully studied by VCD to date.

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