Mechanistic Insights on the Magnesium(II) Ion-Activated Reduction of Methyl Benzoylformate with Chelated NADH Peptide β-Lactam Models

2009 ◽  
Vol 74 (17) ◽  
pp. 6691-6702 ◽  
Author(s):  
Jesus M. Aizpurua ◽  
Claudio Palomo ◽  
Raluca M. Fratila ◽  
Pablo Ferrón ◽  
Ana Benito ◽  
...  
Keyword(s):  
Methyl Benzoylformate

scholarly journals Reduction by a Model of NAD(P)H. XV. Kinetics for the Reduction of Methyl Benzoylformate

1977 ◽  
Vol 50 (9) ◽  
pp. 2385-2386 ◽  
Author(s):  
Atsuyosi Ohno ◽  
Hiroyuki Yamamoto ◽  
Tadashi Okamoto ◽  
Shinzaburo Oka ◽  
Yutaka Ohnishi
Keyword(s):  
Methyl Benzoylformate

Highly reactive and stereospecific reaction of quinoline-type NADH model compounds with methyl benzoylformate

2000 ◽  
Vol 41 (7) ◽  
pp. 1035-1038 ◽  
Author(s):  
Yuji Mikata ◽  
Kayo Hayashi ◽  
Kiyoko Mizukami ◽  
Sawako Matsumoto ◽  
Shigenobu Yano ◽  
...  
Keyword(s):  
Model Compounds ◽  
Methyl Benzoylformate ◽  
Stereospecific Reaction

Enantioselective hydrogenation of methyl benzoylformate on an Ag electrode electrosorbed with cinchonine

RSC Advances ◽  
2014 ◽  
Vol 4 (58) ◽  
pp. 30584-30586 ◽  
Author(s):  
Hengpan Yang ◽  
Ting Lv ◽  
Wenwen Sun ◽  
Yanfang Du ◽  
Huan Wang ◽  
...  
Keyword(s):  
Enantioselective Hydrogenation ◽  
Ag Electrode ◽  
Methyl Benzoylformate ◽  
Excellent Selectivity

Cinchonine was demonstrated to be adsorbed on electrodeposited Ag for enantioselective hydrogenation with moderate ee and excellent selectivity.

Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction

2015 ◽  
Vol 17 (34) ◽  
pp. 21942-21949 ◽  
Author(s):  
Elijah G. Schnitzler ◽  
Mohammad Reza Poopari ◽  
Yunjie Xu ◽  
Wolfgang Jäger
Keyword(s):  
Minimum Energy ◽  
Rotational Spectroscopy ◽  
Internal Dynamics ◽  
Rotational Spectra ◽  
Enantioselective Reduction ◽  
Methyl Benzoylformate ◽  
Methyl Rotation

Rotational spectra of a prochiral ester, methyl benzoylformate, and the product of its enantioselective reduction, (R)-(–)-methyl mandelate, were measured, and minimum energy conformers and methyl rotation barriers were determined.

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