Structural Characterization of Mg-Stabilized Amorphous Calcium Carbonate by Mg-25 Solid-State NMR Spectroscopy

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Amorphous VS4 (a-VS4) is prepared from the crystalline one (c-VS4). Li insertion into a-VS4 involves the amorphous–amorphous phase transition from Peierls-distorted chain-like structure to [VS4]3− tetrahedra-based structure.


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