Structural characterization of interfaces in silica core-alumina shell microspheres by solid-state NMR spectroscopy

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Mihai Vasilescu ◽  
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Miria C. Schumacher ◽  
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Giampietro Cum ◽  
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2019 ◽  
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pp. 23979-23985 ◽  
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Keiji Shimoda ◽  
Kazuto Koganei ◽  
Tomonari Takeuchi ◽  
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Amorphous VS4 (a-VS4) is prepared from the crystalline one (c-VS4). Li insertion into a-VS4 involves the amorphous–amorphous phase transition from Peierls-distorted chain-like structure to [VS4]3− tetrahedra-based structure.


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