Excited-State Dynamics of Chlorine Dioxide in the Condensed Phase from Resonance Raman Intensities

1997 ◽  
Vol 101 (29) ◽  
pp. 5309-5319 ◽  
Author(s):  
Anthony P. Esposito ◽  
Catherine E. Foster ◽  
Robert A. Beckman ◽  
Philip J. Reid
Keyword(s):  
Excited State ◽  
Chlorine Dioxide ◽  
Condensed Phase ◽  
Resonance Raman ◽  
Excited State Dynamics ◽  
Resonance Raman Intensities ◽  
Raman Intensities

Excited-State Reaction Dynamics of Chlorine Dioxide in Water from Absolute Resonance Raman Intensities

1998 ◽  
Vol 102 (20) ◽  
pp. 3514-3523 ◽  
Author(s):  
Catherine E. Foster ◽  
Philip J. Reid
Keyword(s):  
Excited State ◽  
Chlorine Dioxide ◽  
Resonance Raman ◽  
Reaction Dynamics ◽  
Resonance Raman Intensities ◽  
Raman Intensities

scholarly journals Investigating the Environment-dependent Photophysics of Chlorine Dioxide With Resonance Raman Intensities

1999 ◽  
Vol 19 (1-4) ◽  
pp. 305-309
Author(s):  
Anthony P. Esposito ◽  
Catherine E. Foster ◽  
Philip J. Reid
Keyword(s):  
Excited State ◽  
Gas Phase ◽  
Chlorine Dioxide ◽  
Resonance Raman ◽  
Structural Evolution ◽  
Reaction Dynamics ◽  
Intensity Analysis ◽  
Normal Coordinates ◽  
Raman Intensities ◽  
Asymmetric Stretch

The condensed-phase excited-state reaction dynamics of chlorine dioxide are investigated using resonance Raman intensity analysis. Absolute Raman intensities are measured on resonance with the 2B2–2A2 electronic transition and used to establish the excited-state structural evolution which occurs on the 2A2 surface following photoexcitation. Analysis of the intensities demonstrates that excited-state relaxation occurs along all three normal coordinates; however, only modest evolution is observed along the asymmetric stretch. This limited relaxation stands in contrast to the extensive motion along this coordinate in the gas phase. It is proposed that the initial excited-state structural relaxation serves to define the symmetry of the reaction coordinate and thus the mechanism of Cl production following photolysis of OClO.

Excited‐state torsional dynamics of cis‐stilbene from resonance Raman intensities

1984 ◽  
Vol 81 (4) ◽  
pp. 1552-1558 ◽  
Author(s):  
Anne B. Myers ◽  
Richard A. Mathies
Keyword(s):  
Excited State ◽  
Resonance Raman ◽  
Resonance Raman Intensities ◽  
Raman Intensities

scholarly journals Conformational Homogeneity and Excited-State Isomerization Dynamics of the Bilin Chromophore in Phytochrome Cph1 from Resonance Raman Intensities

2012 ◽  
Vol 102 (3) ◽  
pp. 709-717 ◽  
Author(s):  
Katelyn M. Spillane ◽  
Jyotishman Dasgupta ◽  
Richard A. Mathies
Keyword(s):  
Excited State ◽  
Resonance Raman ◽  
Resonance Raman Intensities ◽  
Raman Intensities

Interpretation of Unusual Absorption Bandwidths and Resonance Raman Intensities in Excited State Mixed Valence

2006 ◽  
Vol 110 (1) ◽  
pp. 57-66 ◽  
Author(s):  
Jenny V. Lockard ◽  
Guadalupe Valverde ◽  
Daniel Neuhauser ◽  
Jeffrey I. Zink ◽  
Yun Luo ◽  
...  
Keyword(s):  
Excited State ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Resonance Raman Intensities ◽  
Raman Intensities
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