Laser Flash Photolysis Studies of Radical−Radical Reaction Kinetics:  The HO2+ BrO Reaction

1998 ◽  
Vol 102 (33) ◽  
pp. 6651-6658 ◽  
Author(s):  
J. M. Cronkhite ◽  
R. E. Stickel ◽  
J. M. Nicovich ◽  
P. H. Wine

1995 ◽  
Vol 102 (10) ◽  
pp. 4131-4142 ◽  
Author(s):  
R. P. Thorn ◽  
J. M. Cronkhite ◽  
J. M. Nicovich ◽  
P. H. Wine


1999 ◽  
Vol 103 (17) ◽  
pp. 3228-3236 ◽  
Author(s):  
J. M. Cronkhite ◽  
R. E. Stickel ◽  
J. M. Nicovich ◽  
P. H. Wine




2007 ◽  
Vol 79 (6) ◽  
pp. 993-1001 ◽  
Author(s):  
Robert A. Moss ◽  
Jingzhi Tian ◽  
Gaosheng Chu ◽  
Ronald R. Sauers ◽  
Karsten Krogh-Jespersen

Laser flash photolysis (LFP) of appropriate diazirine precursors afforded the UV spectra of methylchlorocarbene, benzylchlorocarbene, cyclopropylchlorocarbene, and 1-adamantylchlorocarbene. The σ → p transitions of these carbenes were used to directly monitor their reaction kinetics. The unusual and highly reactive N2CO compound, diazirinone, was obtained from the reaction of fluoride ion with p-nitrophenoxychlorodiazirine. Diazirinone fragmented to CO and N2 in a reaction that was exothermic by >90 kcal/mol. Dichlorodiazirine (DCD) was generated by the reaction of chloride ion with p-nitrophenoxychlorodiazirine. Reactions of dichlorocarbene generated from DCD are discussed.





2002 ◽  
Vol 76 (5) ◽  
pp. 480 ◽  
Author(s):  
Xavier Damoiseau ◽  
Francis Tfibel ◽  
Maryse Hoebeke ◽  
Marie-Pierre Fontaine-Aupart


2000 ◽  
Vol 72 (4) ◽  
pp. 451 ◽  
Author(s):  
M. Bazin ◽  
F. Bosca ◽  
M. L. Marin ◽  
M. A. Miranda ◽  
L. K. Patterson ◽  
...  




1999 ◽  
Vol 70 (3) ◽  
pp. 292
Author(s):  
Ann Cantrell ◽  
David J. McGarvey ◽  
Louise Mulroy ◽  
T. George Truscott


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