Rotational Spectra, Molecular Structure, and Electric Dipole Moment of PropanethialS-Oxide

1999 ◽  
Vol 103 (25) ◽  
pp. 4948-4954 ◽  
Author(s):  
Jennifer Z. Gillies ◽  
Elizabeth Cotter ◽  
Charles W. Gillies ◽  
Hugh E. Warner ◽  
Eric Block
Keyword(s):  
Molecular Structure ◽  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Spectra

Adiabatische Korrektur der Born-Oppenheimer-Näherung beim GeS und GeSe / Adiabatic Correction of the Born-Oppenheimer Approximation for GeS and GeSe

1976 ◽  
Vol 31 (3-4) ◽  
pp. 374-380 ◽  
Author(s):  
W. U. Stieda ◽  
E. Tiemann ◽  
T. Törring ◽  
J. Hoeft
Keyword(s):  
Dipole Moment ◽  
High Precision ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Constant ◽  
Frequency Range ◽  
Rotational Spectra ◽  
Oppenheimer Approximation

Abstract The rotational spectra of GeS and GeSe were measured in the frequency range of 66 GHz to 110 GHz with high precision. The breakdown of the Born-Oppenheimer approximation was observed for the rotational constant yol. With the known molecular 37-factor and the electric dipole moment the adiabatic part of the Born-Oppenheimer correction can be extracted from the primary observa-tion on y01. The adiabatic correction is very similar in both molecules but differs from the results in the earlier measurements on PbS.

Rotational Spectra of the Less Common Isotopomers, Electric Dipole Moment and the Double Minimum Inversion Potential of H2O···HCl

2000 ◽  
Vol 104 (30) ◽  
pp. 6970-6978 ◽  
Author(s):  
Z. Kisiel ◽  
B. A. Pietrewicz ◽  
P. W. Fowler ◽  
A. C. Legon ◽  
E. Steiner
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Spectra

Microwave Spectra, Molecular Structure, and Electric Dipole Moment of 1,2-Dithiin

1996 ◽  
Vol 180 (1) ◽  
pp. 139-144 ◽  
Author(s):  
J.Z. Gillies ◽  
C.W. Gillies ◽  
E.A. Cotter ◽  
E. Block ◽  
R. DeOrazio
Keyword(s):  
Molecular Structure ◽  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Microwave Spectra
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