Nanostructured Diblock Copolymer Films:  A Grazing Incidence Small-Angle Neutron Scattering Study†

Langmuir ◽  
2003 ◽  
Vol 19 (19) ◽  
pp. 7778-7782 ◽  
Author(s):  
P. Müller-Buschbaum ◽  
R. Cubitt ◽  
W. Petry

2006 ◽  
Vol 385-386 ◽  
pp. 770-772 ◽  
Author(s):  
L. John R. Foster ◽  
Robert Knott ◽  
Vorapat Sanguanchaipaiwong ◽  
Peter J. Holden


2010 ◽  
Vol 44 (1) ◽  
pp. 84-92 ◽  
Author(s):  
Ezzeldin Metwalli ◽  
Jean-Francois Moulin ◽  
Markus Rauscher ◽  
Gunar Kaune ◽  
Matthias A. Ruderer ◽  
...  

The depth-dependent morphology of the microphase separation structure in thin block copolymer films is examined using non-destructive time-of-flight grazing-incidence small-angle neutron scattering. The structure of a cylinder-forming diblock copolymer, polystyrene(deuterated)-block-polyisoprene, in contact with either a low- or a high-energy substrate surface is investigated. A systematic identification of the components of the polymer film at different depths is achieved by utilizing the material characteristic Yoneda peak. For the polymer film attached to the low-surface-energy aminosilane-coated substrate, a morphology transition from lamellar at the substrate–polymer interface,viaperforated lamellar in the film bulk, to an ill-defined structure at the polymer–air interface is observed. This phase transition along the film normal is due to the competition between the surface-induced morphological changes and the stable cylindrical bulk morphology of the diblock copolymer. In contrast, on the high-energy surface no pronounced ordering is found for the applied conditions.





Langmuir ◽  
1999 ◽  
Vol 15 (2) ◽  
pp. 293-296 ◽  
Author(s):  
Hideki Matsuoka ◽  
Takashi Ikeda ◽  
Hitoshi Yamaoka ◽  
Mitsuhiro Hashimoto ◽  
Toshio Takahashi ◽  
...  


1990 ◽  
Vol 94 (7) ◽  
pp. 3129-3138 ◽  
Author(s):  
V. K. Jindal ◽  
J. Kalus ◽  
H. Pilsl ◽  
H. Hoffmann ◽  
P. Lindner


2017 ◽  
Vol 3 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Gilles E. Möhl ◽  
Ezzeldin Metwalli ◽  
Renaud Bouchet ◽  
Trang N. T. Phan ◽  
Robert Cubitt ◽  
...  




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