Segmental Interaction Parameters of Binary Polymer Mixtures Evaluated from Binodals and from Surface-Segregation Profiles:  Comparison with Small-Angle Neutron Scattering

2000 ◽  
Vol 33 (4) ◽  
pp. 1298-1305 ◽  
Author(s):  
Jacob Klein ◽  
Tobias Kerle ◽  
Florian Zink ◽  
Erika Eiser
1998 ◽  
Vol 31 (22) ◽  
pp. 7962-7965 ◽  
Author(s):  
Osamu Urakawa ◽  
Okimichi Yano ◽  
Qui Tran-Cong ◽  
Alan I. Nakatani ◽  
Charles C. Han

Langmuir ◽  
2008 ◽  
Vol 24 (7) ◽  
pp. 3053-3060 ◽  
Author(s):  
Kevin J. Mutch ◽  
Jeroen S. van Duijneveldt ◽  
Julian Eastoe ◽  
Isabelle Grillo ◽  
Richard K. Heenan

1989 ◽  
Vol 166 ◽  
Author(s):  
Charles C. Han ◽  
Hirokazu Hasegawa ◽  
Takeji Hashimoto ◽  
I. Glen Hargis ◽  
S. L. Aggarwal

ABSTRACTDeuterated polybutadiene and protonated polybutadiene (PBD/PBH) blends with various microstructures have been studied by the small-angle neutron scattering experiments. Correlation length, ξ, zero-wavenumber structure factor, S(q=o), and interaction parameter, Xblend have been obtained. All PBD/PBH blends exhibit UCST behavior. With the use of random copolymer theory, the interaction parameter, Xblend, has been successfully separated into X1, X2 and X3 which are interaction parameters between the same isotope labeled 1,2-unit and 1,4-unit, opposite isotope labeled 1,2-unit and 1,4- unit, and opposite isotope labeled 1,2-unit with 1,2-unit or 1,4-unit with 1,4-unit, respectively.


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