scholarly journals Palladium-Catalyzed, Copper(I)-Mediated Coupling of Boronic Acids and Benzylthiocyanate. A Cyanide-Free Cyanation of Boronic Acids

2006 ◽  
Vol 8 (19) ◽  
pp. 4331-4333 ◽  
Author(s):  
Zhihui Zhang ◽  
Lanny S. Liebeskind
Keyword(s):  
Boronic Acids ◽  
Palladium Catalyzed

Synthesis of Indole/Benzofuran-Containing Diarylmethanes through Palladium-Catalyzed Reaction of Indolylmethyl or Benzofuranylmethyl Acetates with Boronic Acids

Synthesis ◽  
2021 ◽  
Author(s):  
Antonella Goggiamani ◽  
Antonia Iazzetti ◽  
Antonio Arcadi ◽  
Andrea Calcaterra ◽  
Marco Chiarini ◽  
...  
Keyword(s):  
Boronic Acids ◽  
Experimental Procedure ◽  
Palladium Catalyzed ◽  
High Yields ◽  
Reaction Works

AbstractThe palladium-catalyzed synthesis of indole/benzofuran-containing diarylmethanes starting from indolylmethyl or benzofuranylmethyl acetates with boronic acids has been investigated. The success of the reaction is influenced by the choice of precatalyst: with indolylmethyl acetates the reaction works well with [Pd(η3-C3H5)Cl]2/XPhos while with benzofuranylmethyl acetates Pd2(dba)3/XPhos is more efficient. The good to high yields and the simplicity of the experimental procedure make this protocol a versatile synthetic tool for the preparation of 2- and 3-substituted indoles and 2-benzo[b]furans. The methodology can be advantageously extended to the preparation of a key precursor of Zafirlukast.

Efficient synthesis of tetrasubstituted 2,3-allenoates and preliminary studies on bioactivities

2019 ◽  
Vol 6 (3) ◽  
pp. 304-308 ◽  
Author(s):  
Yuan Yao ◽  
Guirong Zhu ◽  
Qin Chen ◽  
Hui Qian ◽  
Shengming Ma
Keyword(s):  
Coupling Reaction ◽  
Boronic Acids ◽  
Efficient Synthesis ◽  
Highly Efficient ◽  
Palladium Catalyzed

A general and highly efficient straightforward protocol for the preparation of tetrasubstituted 2,3-allenoates through a palladium-catalyzed coupling reaction of 3-alkoxycarbonyl propargylic carbonates and boronic acids with commercially available tri(o-tolyl)phosphine as a ligand has been developed.

Palladium-catalyzed carbonylative coupling of pyridine halides with aryl boronic acids

Tetrahedron ◽  
2003 ◽  
Vol 59 (16) ◽  
pp. 2793-2799 ◽  
Author(s):  
Samuel Couve-Bonnaire ◽  
Jean-François Carpentier ◽  
André Mortreux ◽  
Yves Castanet
Keyword(s):  
Boronic Acids ◽  
Palladium Catalyzed

Palladium-Catalyzed Coupling Reaction of α-Diazocarbonyl Compounds with Aromatic Boronic Acids or Halides

Synthesis ◽  
2010 ◽  
Vol 2010 (24) ◽  
pp. 4154-4168 ◽  
Author(s):  
Jianbo Wang ◽  
Cheng Peng ◽  
Guobin Yan ◽  
Yan Wang ◽  
Yubo Jiang ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Boronic Acids ◽  
Palladium Catalyzed

Palladium-Catalyzed Reaction of Boronic Acids with Chiral and Racemic α-Bromo Sulfoxides

2004 ◽  
Vol 69 (23) ◽  
pp. 8070-8076 ◽  
Author(s):  
Nuria Rodríguez ◽  
Ana Cuenca ◽  
Carmen Ramírez de Arellano ◽  
Mercedes Medio-Simón ◽  
Denissa Peine ◽  
...  
Keyword(s):  
Boronic Acids ◽  
Palladium Catalyzed

Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C−H Activation

2008 ◽  
Vol 27 (20) ◽  
pp. 5173-5176 ◽  
Author(s):  
Jean-Ho Chu ◽  
Chin-Chau Chen ◽  
Ming-Jung Wu
Keyword(s):  
Boronic Acids ◽  
Palladium Catalyzed
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