Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

2010 ◽  
Vol 12 (13) ◽  
pp. 3054-3057 ◽  
Author(s):  
Zhaoqun Liu ◽  
Haifeng Du
Keyword(s):  
Allylic Substitutions ◽  
Terminal Alkene ◽  
Palladium Catalyzed ◽  
Hybrid Ligands

P-Stereogenic P/N Hybrid Ligands: A Remarkable Switch in Enantioselectivity in Palladium-Catalyzed Asymmetric Allylation.

ChemInform ◽  
2004 ◽  
Vol 35 (17) ◽  
Author(s):  
Hiroshi Danjo ◽  
Masato Higuchi ◽  
Mitsuhiro Yada ◽  
Tsuneo Imamoto
Keyword(s):  
Asymmetric Allylation ◽  
Palladium Catalyzed ◽  
Hybrid Ligands

C2-Symmetric bis-thioglycosides as new ligands for palladium-catalyzed allylic substitutions

2003 ◽  
Vol 44 (16) ◽  
pp. 3401-3404 ◽  
Author(s):  
Noureddine Khiar ◽  
Cristina S Araújo ◽  
Eleuterio Alvarez ◽  
Inmaculada Fernández
Keyword(s):  
Allylic Substitutions ◽  
Palladium Catalyzed

Palladium catalyzed annulation of 2-iodobiphenyl with a non-terminal alkene enabled by neighboring group assistance

2021 ◽  
Vol 57 (1) ◽  
pp. 121-124
Author(s):  
Bo-Cheng Tang ◽  
Cai He ◽  
Xiang-Long Chen ◽  
Jin-Tian Ma ◽  
Miao Wang ◽  
...  
Keyword(s):  
Neighboring Group ◽  
Terminal Alkene ◽  
Palladium Catalyzed

Neighboring group assisted annulation of non-terminal alkene with 2-iodobiphenyl.

Palladium-catalyzed heck-type cascade cyclization of (Z)-1-iodo-1,6-dienes with N-tosyl hydrazones

2018 ◽  
Vol 16 (40) ◽  
pp. 7356-7360 ◽  
Author(s):  
Jun Li ◽  
Xiaochen Chi ◽  
Long Meng ◽  
Luyang Jiao ◽  
Wenhui Shang ◽  
...  
Keyword(s):  
Cascade Cyclization ◽  
Terminal Alkene ◽  
Palladium Catalyzed

A new way to synthesize tetrahydropyridine derivatives bearing a terminal alkene due to highly regioselective β-H elimination of alkylpalladium species.

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