Palladium catalyzed annulation of 2-iodobiphenyl with a non-terminal alkene enabled by neighboring group assistance

2021 ◽  
Vol 57 (1) ◽  
pp. 121-124
Author(s):  
Bo-Cheng Tang ◽  
Cai He ◽  
Xiang-Long Chen ◽  
Jin-Tian Ma ◽  
Miao Wang ◽  
...  
Keyword(s):  
Neighboring Group ◽  
Terminal Alkene ◽  
Palladium Catalyzed

Neighboring group assisted annulation of non-terminal alkene with 2-iodobiphenyl.

Palladium-catalyzed heck-type cascade cyclization of (Z)-1-iodo-1,6-dienes with N-tosyl hydrazones

2018 ◽  
Vol 16 (40) ◽  
pp. 7356-7360 ◽  
Author(s):  
Jun Li ◽  
Xiaochen Chi ◽  
Long Meng ◽  
Luyang Jiao ◽  
Wenhui Shang ◽  
...  
Keyword(s):  
Cascade Cyclization ◽  
Terminal Alkene ◽  
Palladium Catalyzed

A new way to synthesize tetrahydropyridine derivatives bearing a terminal alkene due to highly regioselective β-H elimination of alkylpalladium species.

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

Synthesis of Allenyl Ketones by the Palladium-Catalyzed Carbonylation of 2-Alkynyl Carbonates in the Presence of Soft Carbon Nucleophiles

Synlett ◽  
1991 ◽  
Vol 1991 (09) ◽  
pp. 697-698 ◽  
Author(s):  
Tadakatsu Mandai ◽  
Hiroaki Kunitomi ◽  
Kiyoto Higashi ◽  
Mikio Kawada ◽  
Jiro Tsuji
Keyword(s):  
Carbon Nucleophiles ◽  
Palladium Catalyzed ◽  
Soft Carbon
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