Synthesis and alkylation of an iron phosphane complex. Crystal and molecular structure determinations for CpFe(CO)2{P(C6H5){N[Si(CH3)3]2}} and CpFe(CO)2{P(CH3)(C6H5){N[Si(CH3)3]2+}} (O3SCF3-)

1988 ◽  
Vol 7 (6) ◽  
pp. 1313-1317 ◽  
Author(s):  
William F. McNamara ◽  
H. U. Reisacher ◽  
Eileen N. Duesler ◽  
Robert T. Paine
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Structure Determinations ◽  
Complex Crystal

Remote and α-Thio Carbene Complexes Derived from an Oxazolinylsubstituted Thiophene

2012 ◽  
Vol 67 (6) ◽  
pp. 509-518 ◽  
Author(s):  
Liliana Dobrzańska ◽  
Gerrit R. Julius ◽  
Elzet Stander-Grobler ◽  
Yolanda Burger (neé Stander) ◽  
Stefan D. Nogai ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Thiophene Ring ◽  
Group 14 ◽  
Carbene Complexes ◽  
Spectroscopic Measurements ◽  
Group 6 ◽  
Structure Determinations ◽  
Oxidative Substitution ◽  
New Compounds

Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.

A stable fullerene complex: crystal and molecular structure of (BDMT-TTeF)(C60)·Cs2

1994 ◽  
Vol 64 (2-3) ◽  
pp. 319-321 ◽  
Author(s):  
Ping Wang ◽  
Wan-Jin Lee ◽  
Irina Shcherbakova ◽  
M.P. Cava ◽  
Robert M. Metzger
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Fullerene Complex ◽  
Complex Crystal
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