Ortho-, Meta-, and Para-Directing Influence of Transition-Metal Fragments in 12-Vertexcloso-Cyclopentadienylmetallaheteroboranes:  Additive Nature of Structural Increments

2006 ◽  
Vol 25 (2) ◽  
pp. 485-490 ◽  
Author(s):  
Farooq Ahmad Kiani ◽  
Matthias Hofmann
Keyword(s):  
Transition Metal ◽  
Structural Increments ◽  
Transition Metal Fragments

scholarly journals Coordination chemistry of phosphinocarbynes: phosphorus vs. carbyne site selectivity

2017 ◽  
Vol 46 (13) ◽  
pp. 4355-4365 ◽  
Author(s):  
Annie L. Colebatch ◽  
Anthony F. Hill
Keyword(s):  
Coordination Chemistry ◽  
Transition Metal ◽  
Site Selectivity ◽  
Transition Metal Fragments

The phosphinocarbyne complex [W(CPPh2)(CO)2(Tp*)] (1: Tp* = hydrotris(dimethylpyrazolyl)borate) coordinates transition metal fragments via the phosphine to form bimetallic species [W{CPPh2RhCl2(Cp*)}(CO)2(Tp*)] (2) and [W(CPPh2AuCl)(CO)2(Tp*)] (3).

Binding phosphinidenes to transition-metal fragments

1985 ◽  
Vol 24 (23) ◽  
pp. 3842-3856 ◽  
Author(s):  
Georges Trinquier ◽  
Guy Bertrand
Keyword(s):  
Transition Metal ◽  
Transition Metal Fragments

Hexa-peri-hexabenzocoronene decorated with an allenylidene ruthenium complex – almost a flyswatter

2020 ◽  
Vol 49 (37) ◽  
pp. 13134-13141
Author(s):  
Rebecca Lorenz ◽  
David Reger ◽  
Ruth Weller ◽  
Norbert Jux ◽  
Nicolai Burzlaff
Keyword(s):  
Transition Metal ◽  
Ruthenium Complex ◽  
Transition Metal Fragments ◽  
Allenylidene Complex

A ruthenium allenylidene complex bearing a hexa-peri-hexabenzocoronene (HBC) substituent was synthesised, resembling yet another strategy to decorate HBCs with transition metal fragments.

scholarly journals Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand

2017 ◽  
Vol 56 (22) ◽  
pp. 14345-14350 ◽  
Author(s):  
Ruth Patchett ◽  
Richard C. Knighton ◽  
James D. Mattock ◽  
Alfredo Vargas ◽  
Adrian B. Chaplin
Keyword(s):  
Transition Metal ◽  
Potassium Binding ◽  
Transition Metal Fragments
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