Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

scholarly journals 16-Electron pentadienyl- and cyclopentadienyl-ruthenium half-sandwich complexes with bis(imidazol-2-imine) ligands and their use in catalytic transfer hydrogenation

2015 ◽  
Vol 44 (26) ◽  
pp. 11717-11724 ◽  
Author(s):  
Thomas Glöge ◽  
Kristof Jess ◽  
Thomas Bannenberg ◽  
Peter G. Jones ◽  
Nadine Langenscheidt-Dabringhausen ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Catalytic Transfer ◽  
Imine Ligands ◽  
Half Sandwich ◽  
Efficient Transfer

Ligand exchange from “protonated open ruthenocene” afforded 16-electron ruthenium half-sandwich complexes as efficient transfer hydrogenation catalysts.

Role of the sulfonamide moiety of Ru(II) half-sandwich complexes in the asymmetric transfer hydrogenation of 3,4-dihydroisoquinolines

2016 ◽  
Vol 118 (1) ◽  
pp. 215-222 ◽  
Author(s):  
Ondřej Matuška ◽  
Jakub Zápal ◽  
Radka Hrdličková ◽  
Miloš Mikoška ◽  
Jan Pecháček ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Half Sandwich

Enantioselective hydrogenation of cyclic imines catalysed by Noyori–Ikariya half-sandwich complexes and their analogues

2016 ◽  
Vol 52 (2) ◽  
pp. 362-365 ◽  
Author(s):  
B. Vilhanová ◽  
J. Václavík ◽  
P. Šot ◽  
J. Pecháček ◽  
J. Zápal ◽  
...  
Keyword(s):  
Trifluoroacetic Acid ◽  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Trifluoroacetic acid activates cyclic imines in a new non-air sensitive asymmetric hydrogenation method. New transfer hydrogenation catalysts are demonstrated.

scholarly journals Quinone Reduction by Organo-Osmium Half-Sandwich Transfer Hydrogenation Catalysts

2021 ◽  
Vol 40 (17) ◽  
pp. 3012-3023
Author(s):  
Elizabeth M. Bolitho ◽  
Nathan G. Worby ◽  
James P. C. Coverdale ◽  
Juliusz A. Wolny ◽  
Volker Schünemann ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalysts ◽  
Quinone Reduction ◽  
Half Sandwich
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