Imine containing C-Symmetric chiral half sandwich η6-p-cymene-Ru(II)- phosphinite complexes: Investigation of their catalytic activity in the asymmetric transfer hydrogenation of ketones

2020 ◽  
Vol 1200 ◽  
pp. 127146
Author(s):  
Najmuldain Abdullah Saleh ◽  
Salih Paşa ◽  
Cezmi Kayan ◽  
Nermin Meriç ◽  
Murat Sünkür ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Half Sandwich

Artificial metalloenzymes derived from bovine β-lactoglobulin for the asymmetric transfer hydrogenation of an aryl ketone – synthesis, characterization and catalytic activity

2014 ◽  
Vol 43 (14) ◽  
pp. 5482-5489 ◽  
Author(s):  
Alice Chevalley ◽  
Mickael V. Cherrier ◽  
Juan C. Fontecilla-Camps ◽  
Mahsa Ghasemi ◽  
Michèle Salmain
Keyword(s):  
Catalytic Activity ◽  
Fatty Acid ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
P Protein ◽  
Artificial Metalloenzymes ◽  
Diimine Complexes ◽  
Β Lactoglobulin ◽  
Aryl Ketone

Protein hybrids resulting from the supramolecular anchoring to bovine β-lactoglobulin of fatty acid-derived Rh(iii) diimine complexes catalysed the asymmetric transfer hydrogenation of trifluoroacetophenone with up to 32% ee.

N,O- vs N,C-Chelation in Half-Sandwich Iridium Complexes: A Dramatic Effect on Enantioselectivity in Asymmetric Transfer Hydrogenation of Ketones

ACS Catalysis ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 8020-8026 ◽  
Author(s):  
Gang Zhou ◽  
Ahmed H. Aboo ◽  
Craig M. Robertson ◽  
Ruixia Liu ◽  
Zhenhua Li ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Iridium Complexes ◽  
Asymmetric Transfer Hydrogenation ◽  
Dramatic Effect ◽  
Half Sandwich

Half-sandwich Ru(η6-C6H6) complexes with chiral aroylthioureas for enhanced asymmetric transfer hydrogenation of ketones – experimental and theoretical studies

2015 ◽  
Vol 5 (10) ◽  
pp. 4790-4799 ◽  
Author(s):  
Mani Mary Sheeba ◽  
Sankaranarayanan Preethi ◽  
A. Nijamudheen ◽  
Manoharan Muthu Tamizh ◽  
Ayan Datta ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Theoretical Studies ◽  
Asymmetric Transfer Hydrogenation ◽  
Experimental And Theoretical Studies ◽  
Half Sandwich

The efficiency of Ru–benzene complexes towards ATH of ketones was studied.

scholarly journals Ruthenium(II) complexes bearing (NNN) ligand: catalytic evaluation of different solvent-mediated coordination modes

2018 ◽  
Vol 96 (1) ◽  
pp. 40-43 ◽  
Author(s):  
Sara Pellegrino ◽  
Giorgio Facchetti ◽  
Raffella Gandolfi ◽  
Marco Fusè ◽  
Emanuela Erba ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Functional Groups ◽  
Transfer Hydrogenation ◽  
Tridentate Ligand ◽  
Asymmetric Transfer Hydrogenation ◽  
Coordination Modes ◽  
Aryl Ketones

A new (NNN) tridentate ligand was prepared, and its ability to coordinate ruthenium(II) was evaluated. The presence of different functional groups on the ligand allows bi- or tri-coordinated complexes to be obtained depending on complexation conditions. The catalytic activity of both bidentate and tridentate complexes was studied in asymmetric transfer hydrogenation of different aryl ketones, showing a comparable behavior of the two complexes in terms of efficiency and stereoselectivity.

Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich
Sign in / Sign up

Export Citation Format

Share Document