Mechanism of Carbon Monoxide Induced N–N Bond Cleavage of Nitrous Oxide Mediated by Molybdenum Complexes: A DFT Study

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An experimental and DFT study of the cleavage of the MOM group mediated by an eco-friendly reagent, bismuth trichloride.


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Utilizing an intramolecular frustrated Lewis pair (FLP) decorated with a strongly donating guanidino moiety enabled the formation of a thermally remarkably stable FLP-CO adduct, which at 120°C underwent CO migration...


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