Trinuclear μ3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ3-Silyl Complex of Ru2Ir into μ-Silyl and μ3-Silylene Complexes

2014 ◽  
Vol 33 (24) ◽  
pp. 7232-7240 ◽  
Author(s):  
Masahiro Nagaoka ◽  
Takanori Shima ◽  
Toshiro Takao ◽  
Hiroharu Suzuki
Keyword(s):  
Silyl Complexes ◽  
Silylene Complexes ◽  
Silyl Complex

1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group

2015 ◽  
Vol 51 (84) ◽  
pp. 15465-15468 ◽  
Author(s):  
Holger Braunschweig ◽  
Rian D. Dewhurst ◽  
Krzysztof Radacki ◽  
Benedikt Wennemann ◽  
Qing Ye
Keyword(s):  
Alkyl Group ◽  
Elimination Reaction ◽  
Silyl Complexes ◽  
Silylene Complexes

The results present a new elimination reaction, the 1,2-alkylborane elimination, as a new route to silylene complexes.

scholarly journals Imido silyl complexes of molybdenum: synthesis, structure, and unusual H2/silane exchange

2020 ◽  
pp. 1-4
Author(s):  
Oleg G. Shirobokov ◽  
Lyudmila G. Kuzmina ◽  
Judith A.K. Howard ◽  
Georgii I. Nikonov
Keyword(s):  
Oxidative Addition ◽  
Silyl Complexes ◽  
Silyl Complex

Reaction of complex (ArN)Mo(H)(Cl)(PMe3)3 (1) with BPh3 and silane H3SiPh affords a new silyl complex (ArN)Mo(SiH2Ph)(Cl)(PMe3)2 (3) that catalyses facile H–H/Si–H exchange. EXSY experiments suggest that this exchange does not involve the classical pathways such as oxidative addition of hydrogen or silane to the complex or σ-bond metathesis. It is suggested that the exchange may occur in an FLP cage comprised by the complex and the silane.

scholarly journals 2-Pyridone-stabilized iridium silylene/silyl complexes: structure and QTAIM analysis

2020 ◽  
Vol 49 (48) ◽  
pp. 17665-17673
Author(s):  
Jefferson Guzmán ◽  
Ana M. Bernal ◽  
Pilar García-Orduña ◽  
Fernando J. Lahoz ◽  
Víctor Polo ◽  
...  
Keyword(s):  
Qtaim Analysis ◽  
Silyl Complexes ◽  
Silylene Complexes

An example of chelate-stabilized iridium-silylene complexes.

Formation of Unique Platinum–Silyl Complexes by the Reactions of a Zero-valent Platinum Complex with Various Trisilanes

2012 ◽  
Vol 41 (11) ◽  
pp. 1538-1540 ◽  
Author(s):  
Hidekazu Arii ◽  
Makiko Takahashi ◽  
Hideyuki Takahashi ◽  
Kunio Mochida ◽  
Takayuki Kawashima
Keyword(s):  
Platinum Complex ◽  
Silyl Complexes
Sign in / Sign up

Export Citation Format

Share Document