Isotopic Investigation of Hydrogen Transfer Related to Cobalt-Catalyzed Free-Radical Chain Transfer

1996 ◽  
Vol 15 (24) ◽  
pp. 5116-5126 ◽  
Author(s):  
Alexei A. Gridnev ◽  
Steven D. Ittel ◽  
Bradford B. Wayland ◽  
Michael Fryd
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Chain Transfer ◽  
Radical Chain ◽  
Isotopic Investigation

Electron Transference in Free Radical Chain Transfer Reactions

Nature ◽  
1964 ◽  
Vol 202 (4933) ◽  
pp. 690-691 ◽  
Author(s):  
JAY K. KOCHI ◽  
DENNIS D. DAVIS
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Transfer Reactions ◽  
Radical Chain

scholarly journals THE STRUCTURE OF BUTADIENE DIMERS PRODUCED BY A FREE-RADICAL CHAIN-TRANSFER MECHANISM

1957 ◽  
Vol 35 (12) ◽  
pp. 1467-1474 ◽  
Author(s):  
L. J. Gendron ◽  
R. V. V. Nicholls
Keyword(s):  
Free Radicals ◽  
Free Radical ◽  
Chain Transfer ◽  
Transfer Mechanism ◽  
The Other ◽  
Chain Transfer Agent ◽  
Radical Chain

Butadiene was dimerized by using acetyl peroxide as source of free radicals and chloroform as solvent and chain-transfer agent. The dimers were identified and their structures were determined by means of ozonolysis and oxidative hydrolysis. It was established that two dimers were produced in nearly equal amount. One dimer was formed only by 1,4-additions, the other only by 1,2-additions. This result implies that polybutadienes may be mixtures of two varieties: one variety resulting from 1,4-additions, the other from 1,2-additions.

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