Electrocatalysis Characteristics of a Polynuclear Cyanide Complex, Ruthenium Purple, for Dihydrogen Oxidation

2004 ◽  
Vol 14 (3) ◽  
pp. 169-176 ◽  
Author(s):  
Toshiyuki Abe ◽  
Toshiki Nagasaka ◽  
Akio Tajiri
1998 ◽  
Vol 63 (5) ◽  
pp. 622-627 ◽  
Author(s):  
Hidetaka Yuge ◽  
Takayoshi Soma ◽  
Takeshi Ken Miyamoto

Crystals of a new clathrate [CuII(hmtd)CuI(CN)3]·CH2Cl2 were afforded from a Me2CO-EtOH-CH2Cl2 solution of a macrocyclic complex CuII(hmtd)CuI(CN)3·2 H2O (hmtd = 5,7,7,12,14,14-hexamethyl- 1,4,8,11-tetraazacyclotetradeca- 4,11-diene). It crystallizes in the monoclinic space group P21/n, a = 7.936(5), b = 18.717(4), c = 17.783(6) Å, β = 98.55(4)°, Z = 4, R = 0.0558 for 1 870 reflections. Unprecedentedly, only one of the three nitrogen-ends of a CuI(CN)3 moiety is coordinated to the square-pyramidal Cu(II) center. The guest CH2Cl2 molecules are captured in the channel between the potlid-shaped [CuII(hmtd)CuI(CN)3] molecules.


2013 ◽  
Vol 30 (12) ◽  
pp. 757-764 ◽  
Author(s):  
Abdoul-Raimi Bouari ◽  
Shamim Ara Begum ◽  
Ynoussa Maiga ◽  
Nosa O. Egiebor

2019 ◽  
Vol 43 (44) ◽  
pp. 17211-17219 ◽  
Author(s):  
Pengbo Jiang ◽  
Lei Ma ◽  
Kaizhi Wang ◽  
Kai Lan ◽  
Zhenzhen Zhan ◽  
...  

Methods of converting carbon dioxide into valuable chemicals are of great demand but their development is still challenging.


Nature ◽  
1949 ◽  
Vol 163 (4145) ◽  
pp. 566-567 ◽  
Author(s):  
H. M. POWELL ◽  
J. H. RAYNER

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