Main-group and transition-metal complexes of 1-thia-4,7-diazacyclononane, [9]aneN2S. Crystal structures of [VOCl2([9]aneN2S)]· MeCN, [Fe([9]aneN2S)2][ClO4]2, [Zn([9]aneN2S)2][PF6]2, [Ru(cym)([9]aneN2S)][BPh4]Cl2·M eCN (cym = p-cymene), [RhCl3([9]aneN2S)]·H2O and [Tl([9]aneN2S)][ClO4]

1997 ◽  
pp. 501-508 ◽  
Author(s):  
Ulrich Heinzel ◽  
Andreas Henke ◽  
Rainer Mattes
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
Main Group

scholarly journals Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes

2017 ◽  
Vol 375 (2101) ◽  
pp. 20170002 ◽  
Author(s):  
R. Morris Bullock ◽  
Geoffrey M. Chambers
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Complexes ◽  
Main Group ◽  
Lewis Base ◽  
Metal Compounds ◽  
Metal Catalysis ◽  
Heterolytic Cleavage ◽  
Lewis Pairs

This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

New main-group and early transition-metal complexes of mono-pendant arm triazacyclononane ligands

2001 ◽  
pp. 170-180 ◽  
Author(s):  
Sergei Y. Bylikin ◽  
David A. Robson ◽  
Nigel A. H. Male ◽  
Leigh H. Rees ◽  
Philip Mountford ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Early Transition Metal ◽  
Pendant Arm ◽  
Early Transition

Syntheses and Crystal Structures of Two New Pentaborates Templated by Transition-Metal Complexes

2014 ◽  
Vol 25 (5) ◽  
pp. 1295-1305 ◽  
Author(s):  
Qin Meng ◽  
Guo-Ming Wang ◽  
Huan He ◽  
Bai-Feng Yang ◽  
Guo-Yu Yang
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes

Silicon-Containing Main Group - Transition Metal Complexes

2008 ◽  
pp. 199-200
Author(s):  
Martin Strampfer ◽  
Michael Knorr ◽  
Pierre Braunstein
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group
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