The first direct observation of N–O bond cleavage in the oxidative addition of an oxime to a metal centre. Synthesis and crystal structure of the methyleneamide complex trans-[Re(OH)(NCMe2)(Ph2PCH2CH2PPh2)2][HSO4]

1998 ◽  
pp. 325-326 ◽  
Author(s):  
Cristina M. P. Ferreira ◽  
M. Fátima C. Guedes da Silva ◽  
Vadim Yu. Kukushkin ◽  
João J. R. Fraústo da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Crystal Structure ◽  
Direct Observation ◽  
Bond Cleavage ◽  
Oxidative Addition ◽  
Metal Centre ◽  
Synthesis And Crystal Structure

Oxidative addition of OH bond to a metal centre: synthesis and crystal structure of trans-(PhO)(H)Pd(PCy3)2·PhOH

1987 ◽  
Vol 334 (3) ◽  
pp. C46-C48 ◽  
Author(s):  
Dario Braga ◽  
Piera Sabatino ◽  
Cristina Di Bugno ◽  
Piero Leoni ◽  
Marco Pasquali
Keyword(s):  
Crystal Structure ◽  
Oxidative Addition ◽  
Metal Centre ◽  
Synthesis And Crystal Structure

Cluster Chemistry. XLI. P-C Bond Cleavage Reactions of Ru3(µ-dppm)(CO)10. Synthesis and Crystal Structure of Ru3[µ3-PPhCH2PPh(C6H4)](CO)9

1985 ◽  
Vol 38 (9) ◽  
pp. 1301 ◽  
Author(s):  
MI Bruce ◽  
PA Humphrey ◽  
BW Skelton ◽  
AH White ◽  
ML Williams
Keyword(s):  
Crystal Structure ◽  
Bond Cleavage ◽  
Title Complex ◽  
Cluster Chemistry ◽  
Synthesis And Crystal Structure ◽  
Cleavage Reactions

Thermolysis of Ru3(μ- dppm )(CO)10 (1) results in cyclometallation and dephenylation to give the title complex. This complex is also formed, together with Ru3(μ-H)(μ3-PPhCH2PPh2(CO)9, from reaction between (1) with HC5(CO2Me)5.

Synthesis and coordination chemistry of the PPN ligand 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine

2017 ◽  
Vol 73 (11) ◽  
pp. 917-922
Author(s):  
Delong Han ◽  
Benjamin Andres ◽  
Anke Spannenberg ◽  
Torsten Beweries
Keyword(s):  
Crystal Structure ◽  
Coordination Chemistry ◽  
Metal Centre ◽  
Synthesis And Crystal Structure

The synthesis and crystal structure of the multidentate PPN ligand 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine (L), C19H35NP2, are described. In the isostructural tetrahedral Fe and Co complexes of type LMCl2 (M = Fe, Co), namely {2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine-κ2 P,N}dichloridoiron(II), [FeCl2(C19H35NP2)], and {2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine-κ2 P,N}dichloridocobalt(II), [CoCl2(C19H35NP2)], the ligand adopts a bidentate P,N-coordination, whereas in the case of the octahedral Mn complex {2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine-κ2 P,P′}bromidotricarbonylmanganese(I), [MnBr(C19H35NP2)(CO)3], the ligand coordinates via both P atoms to the metal centre.

Simple design for metal-based halogen-bonded cocrystals utilizing the M–Cl⋯I motif

CrystEngComm ◽  
2018 ◽  
Vol 20 (39) ◽  
pp. 5955-5963 ◽  
Author(s):  
Katarina Lisac ◽  
Dominik Cinčić
Keyword(s):  
Crystal Structure ◽  
Chlorine Atom ◽  
Structure Analysis ◽  
Halogen Bonding ◽  
Crystal Structure Analysis ◽  
Simple Design ◽  
Metal Centre ◽  
Synthesis And Crystal Structure

The halogen bonding proclivity of the chlorine atom coordinated to the Co(ii) metal centre has been explored by synthesis and crystal structure analysis of a family of 12 novel metal-based halogen-bonded cocrystals with iodine-based donors.

Synthesis and crystal structure analysis of ferrocenylthiosemicarbazone complexes of palladium(II): Unusual σPd–C bond cleavage

Polyhedron ◽  
2006 ◽  
Vol 25 (6) ◽  
pp. 1449-1456 ◽  
Author(s):  
Marta Mariño ◽  
Eduardo Gayoso ◽  
José M. Antelo ◽  
Luis A. Adrio ◽  
Jesús J. Fernández ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Bond Cleavage ◽  
Crystal Structure Analysis ◽  
Synthesis And Crystal Structure
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