Halogen Bonding
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2022 ◽  
pp. 27-67
Author(s):  
Revannath L. Sutar ◽  
Stefan M. Huber *
Keyword(s):  

2022 ◽  
Author(s):  
Kazuki Matsuo ◽  
Eiji Yamaguchi ◽  
Akichika Itoh

This study investigates the photo-induced C–X borylation reaction of aryl halides by forming a halogen-bonding complex. The method employs 2-naphthol as a halogen-bonding acceptor and proceeds under mild conditions without a photoredox catalyst under 420 nm blue light irradiation. The method is highly chemoselective, broadly functional group tolerant, and provides concise access to corresponding boronate esters. Mechanistic studies reveal that forming the halogen-bonding complex between aryl halide and naphthol acts as an electron donor-acceptor complex to furnish aryl radicals through photo-induced electron transfer.


Author(s):  
Tian Zhao ◽  
Vincent Lynch ◽  
Jonathan L. Sessler

Inspired by the tetracationic “Texas-sized” molecular box, a neutral analogue containing four iodotriazole halogen bond-promoting subunits (“Ibox”) was synthesized. This new macrocycle was prepared by means of azide-alkyne click chemistry....


Polyhedron ◽  
2022 ◽  
pp. 115644
Author(s):  
Mikhail A. Bondarenko ◽  
Pavel A. Abramov ◽  
Alexander S. Novikov ◽  
Maxim N. Sokolov ◽  
Sergey A. Adonin
Keyword(s):  

2021 ◽  
pp. 413-426
Author(s):  
Revannath L. Sutar ◽  
Stefan M. Huber

2021 ◽  
Author(s):  
Pierangelo Metrangolo ◽  
Laura Canil ◽  
Antonio Abate ◽  
Giancarlo Terraneo ◽  
Gabriella Cavallo

Author(s):  
Pierangelo Metrangolo ◽  
Laura Canil ◽  
Antonio Abate ◽  
Giancarlo Terraneo ◽  
Gabriella Cavallo

2022 ◽  
Author(s):  
Asia Marie S Riel ◽  
Daniel Adam Decato ◽  
Jiyu Sun ◽  
Orion Berryman

Recent results indicate a halogen bond donor is strengthened through direct interaction with a hydrogen bond to the electron-rich belt of the halogen. Here, this Hydrogen Bond enhanced Halogen Bond...


2021 ◽  
Author(s):  
Tarannum Tasnim ◽  
Calvin Ryan ◽  
Miranda L. Christensen ◽  
Christopher J. Fennell ◽  
Spencer P. Pitre

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