Diverse mixed-ligand metal complexes with in situ generated 5-(pyrazinyl)tetrazolate chelating-bridging ligand: in situ synthesis, crystal structures, magnetic and luminescent properties

CrystEngComm ◽  
2011 ◽  
Vol 13 (1) ◽  
pp. 230-242 ◽  
Author(s):  
En-Cui Yang ◽  
Yan Feng ◽  
Zhong-Yi Liu ◽  
Tian-Yu Liu ◽  
Xiao-Jun Zhao
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Luminescent Properties ◽  
In Situ Synthesis ◽  
Mixed Ligand ◽  
Bridging Ligand

Crystal structures, in situ synthesis in aqua conditions and luminescent properties of benzimidazole ligands and cadmium coordination complexes

2015 ◽  
Vol 435 ◽  
pp. 215-222 ◽  
Author(s):  
Yong-Cong Ou ◽  
Han-Cheng Chen ◽  
Yuan-Hao Liang ◽  
Jun-Jie Tang ◽  
Shao-Bin Feng ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Luminescent Properties ◽  
Coordination Complexes ◽  
In Situ Synthesis

Symmetrical tetra-β″-sulfoleno-meso-aryl-porphyrins — synthesis, spectroscopy and structural characterization

2014 ◽  
Vol 18 (01n02) ◽  
pp. 115-122 ◽  
Author(s):  
Srinivas Banala ◽  
Klaus Wurst ◽  
Bernhard Kräutler
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Structural Characterization ◽  
Building Blocks ◽  
Cycloaddition Reactions ◽  
One Pot

We report here the preparation (in "one-pot") of a tetra-β″-sulfoleno-meso-aryl-porphyrin in about 80% yield by using an optimized modification of Lindsey's variant of the Adler–Longo approach. The Zn ( II )-, Cu ( II )- and Ni ( II )-complexes of the symmetrical porphyrin were prepared and characterized spectroscopically. Crystal structures of the fluorescent Zn ( II )- and of the non-fluorescent Ni ( II )-tetra-β″-sulfoleno-meso-aryl-porphyrinates showed the highly substituted porphyrin ligands to be nearly perfectly planar. The Zn ( II )-complex of this porphyrin has been used as a thermal precursor of a reactive diene, and — formally — of lateral and diagonal bis-dienes, of a tris-diene and of a tetra-diene, which all underwent [4 + 2]-cycloaddition reactions in situ with a range of dienophiles. Thus, the tetra-β″-sulfoleno-meso-aryl-porphyrin and its metal complexes represent reactive building blocks, "programmed" for the syntheses of symmetrical and highly functionalized porphyrins.

Novel metal complexes containing a chiral trinitrogen isoindoline-based pincer ligand: in situ synthesis and structural characterization

2010 ◽  
Vol 39 (44) ◽  
pp. 10671 ◽  
Author(s):  
Jessica L. Cryder ◽  
Andrew J. Killgore ◽  
Curtis Moore ◽  
James A. Golen ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Structural Characterization ◽  
In Situ Synthesis ◽  
Pincer Ligand

Two new CuI compounds with zwitterionic tetrazolate ligand: In situ synthesis, crystal structures, luminescence and photocatalytic properties

2015 ◽  
Vol 232 ◽  
pp. 19-25 ◽  
Author(s):  
Jian-Yong Zhang ◽  
Yuan-Yuan Xing ◽  
Qing-Wei Wang ◽  
Na Zhang ◽  
Wei Deng ◽  
...  
Keyword(s):  
Crystal Structures ◽  
In Situ Synthesis ◽  
Photocatalytic Properties

In situ synthesis, crystal structures, and luminescence of two new tetrazole complexes

2010 ◽  
Vol 63 (17) ◽  
pp. 3101-3107 ◽  
Author(s):  
Yun-Zhi Tang ◽  
Zan Cao ◽  
He-Rui Wen ◽  
Su-Lan Liao ◽  
Shuai Huang ◽  
...  
Keyword(s):  
Crystal Structures ◽  
In Situ Synthesis
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