Novel metal complexes containing a chiral trinitrogen isoindoline-based pincer ligand: in situ synthesis and structural characterization

2010 ◽  
Vol 39 (44) ◽  
pp. 10671 ◽  
Author(s):  
Jessica L. Cryder ◽  
Andrew J. Killgore ◽  
Curtis Moore ◽  
James A. Golen ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Structural Characterization ◽  
In Situ Synthesis ◽  
Pincer Ligand

Symmetrical tetra-β″-sulfoleno-meso-aryl-porphyrins — synthesis, spectroscopy and structural characterization

2014 ◽  
Vol 18 (01n02) ◽  
pp. 115-122 ◽  
Author(s):  
Srinivas Banala ◽  
Klaus Wurst ◽  
Bernhard Kräutler
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Structural Characterization ◽  
Building Blocks ◽  
Cycloaddition Reactions ◽  
One Pot

We report here the preparation (in "one-pot") of a tetra-β″-sulfoleno-meso-aryl-porphyrin in about 80% yield by using an optimized modification of Lindsey's variant of the Adler–Longo approach. The Zn ( II )-, Cu ( II )- and Ni ( II )-complexes of the symmetrical porphyrin were prepared and characterized spectroscopically. Crystal structures of the fluorescent Zn ( II )- and of the non-fluorescent Ni ( II )-tetra-β″-sulfoleno-meso-aryl-porphyrinates showed the highly substituted porphyrin ligands to be nearly perfectly planar. The Zn ( II )-complex of this porphyrin has been used as a thermal precursor of a reactive diene, and — formally — of lateral and diagonal bis-dienes, of a tris-diene and of a tetra-diene, which all underwent [4 + 2]-cycloaddition reactions in situ with a range of dienophiles. Thus, the tetra-β″-sulfoleno-meso-aryl-porphyrin and its metal complexes represent reactive building blocks, "programmed" for the syntheses of symmetrical and highly functionalized porphyrins.

In Situ Synthesis of Trisubstituted Methanol Ligands and Their Potential as One-Pot Generators of Cubane-like Metal Complexes

2006 ◽  
Vol 12 (27) ◽  
pp. 7095-7102 ◽  
Author(s):  
Brendan F. Abrahams ◽  
Timothy A. Hudson ◽  
Richard Robson
Keyword(s):  
Metal Complexes ◽  
In Situ Synthesis ◽  
One Pot
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