Iridium(i) N-heterocyclic carbene complexes of benzimidazol-2-ylidene: effect of electron donating groups on the catalytic transfer hydrogenation reaction

2013 ◽  
Vol 42 (20) ◽  
pp. 7305-7311 ◽  
Author(s):  
Süleyman Gülcemal ◽  
Aytaç Gürhan Gökçe ◽  
Bekir Çetinkaya
Keyword(s):  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Carbene Complexes ◽  
Catalytic Transfer ◽  
Transfer Hydrogenation Reaction ◽  
Electron Donating Groups

Transfer hydrogenation of cinnamaldehyde with 2-propanol on Al2O3 and SiO2–Al2O3 catalysts: role of Lewis and Brønsted acidic sites

2017 ◽  
Vol 7 (19) ◽  
pp. 4511-4519 ◽  
Author(s):  
Zhan-Kun Gao ◽  
Yong-Chun Hong ◽  
Zhun Hu ◽  
Bo-Qing Xu
Keyword(s):  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Basic Sites ◽  
Acidic Sites ◽  
Catalytic Transfer ◽  
Transfer Hydrogenation Reaction

Neither surface Brønsted acidic nor basic sites are involved in the catalytic transfer hydrogenation reaction of cinnamaldehyde with 2-propanol.

scholarly journals Catalytic transfer hydrogenation in γ-valerolactone-based ionic liquids

RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 72529-72535 ◽  
Author(s):  
Andrea Strádi ◽  
Márk Molnár ◽  
Péter Szakál ◽  
Gábor Dibó ◽  
Dániel Gáspár ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Environmentally Benign ◽  
Organic Substrates ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer ◽  
Transfer Hydrogenation Reaction

The combination of transfer hydrogenation reaction with the advantages of γ-valerolactone-based ionic liquids could result in an environmentally benign method for the reduction of organic substrates.

Palladium nanoparticles supported on nanosheet-like graphitic carbon nitride for catalytic transfer hydrogenation reaction

2020 ◽  
Vol 10 (23) ◽  
pp. 7883-7893
Author(s):  
Yan-Jhu Chou ◽  
Hao-Chuan Ku ◽  
Cheng-Chi Chien ◽  
Chechia Hu ◽  
Wen-Yueh Yu
Keyword(s):  
Palladium Nanoparticles ◽  
Carbon Nitride ◽  
Pd Nanoparticles ◽  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Ambient Conditions ◽  
Catalytic Transfer ◽  
Transfer Hydrogenation Reaction ◽  
Pyridinic N

Pd/g-C3N4 catalysts with well-dispersed, electron-enriched Pd nanoparticles immobilized on pyridinic N atoms of g-C3N4 are active for catalytic transfer hydrogenation under ambient conditions.

scholarly journals Fischer Carbene Complexes of Iridium(I) for Application in Catalytic Transfer Hydrogenation

2020 ◽  
Vol 59 (7) ◽  
pp. 4810-4815
Author(s):  
G. Kabelo Ramollo ◽  
Ian Strydom ◽  
Manuel A. Fernandes ◽  
Andreas Lemmerer ◽  
Stephen O. Ojwach ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Fischer Carbene Complexes ◽  
Carbene Complexes ◽  
Fischer Carbene ◽  
Catalytic Transfer

Hydroxyl and ester functionalized N-heterocyclic carbene complexes of iridium(i): efficient catalysts for transfer hydrogenation reactions

RSC Advances ◽  
2014 ◽  
Vol 4 (50) ◽  
pp. 26222-26230 ◽  
Author(s):  
Derya Gülcemal ◽  
Aytaç Gürhan Gökçe ◽  
Süleyman Gülcemal ◽  
Bekir Çetinkaya
Keyword(s):  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Carbene Complexes ◽  
Aldehydes And Ketones ◽  
Hydrogenation Reactions ◽  
Transfer Hydrogenation Reaction

Iridium(i)–NHC catalyzed transfer hydrogenation reaction of aldehydes and ketones with up to 10 000 TON has been achieved.

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