A new procedure for the synthesis of π-conjugated polymers via ligand-free iron(iii)-catalyzed oxidative homocoupling reaction of grignard reagents

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A ligand-free iron-catalyzed method for the oxygenation of benzylic sp3 C–H bonds by molecular oxygen (1 atm) using a thiyl radical as a cocatalyst has been developed.


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Xiao‐Shui Peng ◽  
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