A tridentate unsaturated tertiary phosphine obtained by dehydrogenation of 2,2′-bis(diphenylphosphino)bibenzyl in the presence of rhodium complexes; X-ray crystal structure of the chelate olefin complex RhCl(o-Ph2P·C6H4·CH:CH·C6H4·PPh2-o),CH2Cl2

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39720001011 ◽

1972 ◽

Vol 0 (18) ◽

pp. 1011-1012 ◽

Author(s):

M. A. Bennett ◽

P. W. Clark ◽

G. B. Robertson ◽

P. O. Whimp

Keyword(s):

Crystal Structure ◽

Rhodium Complexes ◽

Tertiary Phosphine ◽

Download Full-text

Preparation and characterization of some ruthenium(II) porphyrins containing tertiary phosphine axial ligands, including the crystal structure of (octaethylporphinato)bis(triphenylphosphine)ruthenium(II)

Canadian Journal of Chemistry ◽

10.1139/v84-127 ◽

1984 ◽

Vol 62 (4) ◽

pp. 755-762 ◽

Author(s):

Sara Ariel ◽

David Dolphin ◽

George Domazetis ◽

Brian R. James ◽

Tak W. Leung ◽

...

Keyword(s):

Crystal Structure ◽

Phosphine Ligands ◽

Tertiary Phosphine ◽

X Ray ◽

Porphyrin Complex ◽

H Nmr ◽

Axial Ligands ◽

Nmr Data ◽

Phosphine Complex

The ruthenium(II) porphyrin complex Ru(OEP)(PPh3)2 (OEP = the dianion of octaethylporphyrin) has been prepared from Ru(OEP)(CO)EtOH, and the X-ray crystal structure determined; as expected, the six-coordinate ruthenium is situated in the porphyrin plane and has two axial phosphine ligands. Synthesized also from the carbonyl(ethanol) precursors were the corresponding tris(p-methoxyphenyl)phosphine complex, and the Ru(TPP)L2 (TPP = the dianion of tetraphenylporphyrin, L = PPh3, P(p-CH3OC6H4)3, P″Bu3) and Ru(TPP)(CO)PPh3 complexes. Optical and 1H nmr data are presented for the complexes in solution. In some cases dissociation of a phosphine ligand to generate five-coordinate species occurs and this has been studied quantitatively in toluene at 20 °C for the Ru(OEP)L2 and Ru(TPP)L2 systems.

Download Full-text

Rhodium complexes possessing the unidentate anion of 2,4-pentanedione as a ligand; X-ray crystal structure of carbonyl(2,4-pentanedionato-O)bis(tri-isopropylphosphine)rhodium(I)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9880000895 ◽

1988 ◽

pp. 895 ◽

Author(s):

Shin-ichi Yoshida ◽

Yuji Ohgomori ◽

Yoshihisa Watanabe ◽

Kazumasa Honda ◽

Midori Goto ◽

...

Keyword(s):

Crystal Structure ◽

Rhodium Complexes ◽

Download Full-text

Tertiary phosphine adducts of manganese (II) dihalides. The X-ray crystal structure of di-iodo(phenyldimethylphosphine)manganese(II)

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39840000305 ◽

1984 ◽

pp. 305 ◽

Author(s):

Brian Beagley ◽

Josie C. Briggs ◽

Afshien Hossiny ◽

W. Eugene Hill ◽

Trevor J. King ◽

...

Keyword(s):

Crystal Structure ◽

Tertiary Phosphine ◽

Download Full-text

ChemInform Abstract: X-Ray Crystal Structure and Structural Dynamics of [Ir3{mu-(Ph2PCH2)2AsPh}2(mu-CO)2(CO)2(mu-Cl)Cl]+ and Related Rhodium Complexes.

Chemischer Informationsdienst ◽

10.1002/chin.198634299 ◽

1986 ◽

Vol 17 (34) ◽

Author(s):

A. L. BALCH ◽

L. A. FOSSETT ◽

R. R. GUIMERANS ◽

M. M. OLMSTEAD ◽

P. E. JUN. REEDY

Keyword(s):

Crystal Structure ◽

Structural Dynamics ◽

Rhodium Complexes ◽

Download Full-text

ChemInform Abstract: Tertiary Phosphine Complexes of Gold(I) and Gold(III) with Imido Ligands:1H,31P, and15N NMR Spectroscopy, Antiinflammatory Activity, and X-Ray Crystal Structure of (Phthalimido)(triethylphosphine)gold(I).

Chemischer Informationsdienst ◽

10.1002/chin.198605283 ◽

1986 ◽

Vol 17 (5) ◽

Author(s):

S. J. BERNERS PRICE ◽

M. J. DIMARTINO ◽

D. T. HILL ◽

R. KURODA ◽

M. A. MAZID ◽

...

Keyword(s):

Crystal Structure ◽

Nmr Spectroscopy ◽

Antiinflammatory Activity ◽

Tertiary Phosphine ◽

X Ray ◽

Phosphine Complexes

Download Full-text

Palladium(0) complexes formed by a chelating olefinic tertiary phosphine. Synthesis, fluxional behavior, and x-ray crystal structure of Pd(o-CH2:CHC6H4PPh2)2, a three-coordinate complex containing a weak interaction between the metal atom and an .alpha.-vinylic hydrogen atom

Organometallics ◽

10.1021/om00096a028 ◽

1988 ◽

Vol 7 (6) ◽

pp. 1403-1409 ◽

Author(s):

Martin A. Bennett ◽

Chindarat. Chiraratvatana ◽

Glen B. Robertson ◽

Uncharee. Tooptakong

Keyword(s):

Crystal Structure ◽

Hydrogen Atom ◽

Weak Interaction ◽

Tertiary Phosphine ◽

Download Full-text

The co-ordination of small molecules by manganese(II) phosphine complexes. Part 14. Some novel mixed tertiary phosphine–t-butyl isocyanide complexes of manganese(II): [MnBr2(CNBut)(PPhMe2)] and [Mn(CNBut)4(PR3)2]2+(PR3= PPhMe2, PPh2Me, PPhEt2, or PPrn3), and the X-ray crystal structure of bis(dimethylphenylphosphine)tetrakis(t-butyl isocyanide)manganese(II) bis[tribromo(dimethylphenylphosphine oxide)manganate(II)], [Mn(CNBut)4(PPhMe2)2][MnBr3(OPPhMe2)]2

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9880002261 ◽

1988 ◽

pp. 2261-2266 ◽

Author(s):

Brian Beagley ◽

Christopher G. Benson ◽

George A. Gott ◽

Charles A. McAuliffe ◽

Robin G. Pritchard ◽

...

Keyword(s):

Crystal Structure ◽

Small Molecules ◽

Tertiary Phosphine ◽

X Ray ◽

Phosphine Complexes

Download Full-text

The X-ray crystal structure of [Zn(PEt3)I2]2, the first 1:1 zinc(II) complex of a tertiary phosphine of low steric requirements, prepared by the reaction of unactivated zinc metal with diiodotriethylphosphorane

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39920000944 ◽

1992 ◽

pp. 944 ◽

Author(s):

Neil Bricklebank ◽

Stephen M. Godfrey ◽

Charles A. McAuliffe ◽

Anthony G. Mackie ◽

Robin G. Pritchard

Keyword(s):

Crystal Structure ◽

Tertiary Phosphine ◽

X Ray ◽

Download Full-text

Hydrido heterobimetallic bis(diphenylphosphino)methane-bridged ruthenium-rhodium complexes. Activation of a phosphorus-carbon bond of bis(diphenylphosphino)methane to give a heterobimetallic ruthenium-rhodium complex containing a trans-hydridophenylruthenium moiety. X-ray crystal structure of RuRhH(C6H5)(C8H12)[C6H5PCH2P(C6H5)2][(C6H5)2PCH2P(C6H5)2].cntdot.0.5C6H5CH3

Organometallics ◽

10.1021/om00124a023 ◽

1985 ◽

Vol 4 (5) ◽

pp. 935-937 ◽

Author(s):

Beatrice. Delavaux ◽

Bruno. Chaudret ◽

Francoise. Dahan ◽

Rene. Poilblanc

Keyword(s):

Crystal Structure ◽

Rhodium Complex ◽

Rhodium Complexes ◽

Carbon Bond ◽

Download Full-text

The co-ordination of small molecules by manganese(II) phosphine complexes. Part 8. Irreversible oxidation of trimethylphosphinemanganese(II) dihalides, [MnX2(PMe3)](X = Cl, Br, or I), to bis(trimethylphosphine)manganese(III) trihalides, [MnX3(PMe3)2]. X-Ray crystal structure of trans-tri-iodobis-(trimethylphosphine)manganese(III), the first example of a trigonal-bipyramidal manganese(III) tertiary phosphine complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9870001999 ◽

1987 ◽

pp. 1999 ◽

Author(s):

Brian Beagley ◽

Charles A. McAuliffe ◽

Karl Minten ◽

Robin G. Pritchard

Keyword(s):

Crystal Structure ◽

Small Molecules ◽

Tertiary Phosphine ◽

X Ray ◽

Phosphine Complexes ◽

Trigonal Bipyramidal ◽

Irreversible Oxidation ◽

Phosphine Complex

Download Full-text