C–O bond cleavage in alkenyl carboxylates promoted by transition-metal hydrides

1974 ◽  
pp. 523b-524 ◽  
Author(s):  
Sanshiro Komiya ◽  
Akio Yamamoto
Keyword(s):  
Transition Metal ◽  
Bond Cleavage ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation

Positive ions of the first‐ and second‐row transition metal hydrides

1987 ◽  
Vol 87 (1) ◽  
pp. 481-492 ◽  
Author(s):  
Lars G. M. Pettersson ◽  
Charles W. Bauschlicher ◽  
Stephen R. Langhoff ◽  
Harry Partridge
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Positive Ions
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