transition metal hydrides
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Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity

2021 ◽  
Vol 438 ◽  
pp. 213799
Author(s):  
Natalia V. Belkova ◽  
Oleg A. Filippov ◽  
Elena S. Osipova ◽  
Sergey V. Safronov ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Pincer Ligands ◽  
Transition Metal Hydrides

The optical properties and carrier mobility in monolayer MH$_3$(M = Co, Rh and Ir)

2021 ◽  
Author(s):  
Yang Yang ◽  
Jimin Shang ◽  
Zijiong Li ◽  
Hong Yan Lu ◽  
Yandong Ma
Keyword(s):  
Optical Properties ◽  
Transition Metal ◽  
Electronic Structures ◽  
Carrier Mobility ◽  
Phonon Dispersion ◽  
Metal Hydrides ◽  
First Principle ◽  
Two Dimensional ◽  
First Principle Calculations ◽  
Transition Metal Hydrides

A new serial of two-dimensional transition metal hydrides MH$_3$ (M = Co, Rh, Ir) is investigated by first principle calculations. Electronic structures, phonon dispersion, optical absorptions, and carrier mobilities are...

scholarly journals Na3FeH7 and Na3CoH6: Hydrogen-Rich First-Row Transition Metal Hydrides from High Pressure Synthesis

2020 ◽  
Vol 59 (22) ◽  
pp. 16467-16473
Author(s):  
Kristina Spektor ◽  
Wilson A. Crichton ◽  
Stanislav Filippov ◽  
Sergei I. Simak ◽  
Andreas Fischer ◽  
...  
Keyword(s):  
High Pressure ◽  
Transition Metal ◽  
Metal Hydrides ◽  
High Pressure Synthesis ◽  
Transition Metal Hydrides ◽  
Pressure Synthesis

Thermodynamic and kinetic hydricity of transition metal hydrides

2020 ◽  
Vol 49 (22) ◽  
pp. 7929-7948 ◽  
Author(s):  
Kelsey R. Brereton ◽  
Nicholas E. Smith ◽  
Nilay Hazari ◽  
Alexander J. M. Miller
Keyword(s):  
Transition Metal ◽  
Case Studies ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

This review of thermodynamic and kinetic hydricity provides conceptual overviews, tutorials on how to determine hydricity both experimentally and computationally, and salient case studies.

Solvent-free synthesis and reactivity of nickel(ii) borohydride and nickel(ii) hydride

2019 ◽  
Vol 21 (10) ◽  
pp. 2752-2758 ◽  
Author(s):  
Sakthi Raje ◽  
Raja Angamuthu
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
High Reactivity ◽  
Solvent Free ◽  
High Yield ◽  
Organic Transformations ◽  
Transition Metal Hydrides ◽  
Solvent Free Synthesis

Transition metal-hydrides are highly useful in organic transformations of industrial importance yet synthesizing them or their precursor metal-borohydrides in high yield is cumbersome due to their high reactivity and sensitivity towards air and many common solvents.

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