The cobalt corrole catalyzed hydrogen evolution reaction: surprising electronic effects and characterization of key reaction intermediates

2014 ◽  
Vol 50 (21) ◽  
pp. 2725-2727 ◽  
Author(s):  
Atif Mahammed ◽  
Biswajit Mondal ◽  
Atanu Rana ◽  
Abhishek Dey ◽  
Zeev Gross
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Reaction Intermediates ◽  
Electronic Effects ◽  
Surprising Effect

The proton-activating intermediate in the cobalt corrole catalyzed hydrogen evolution reaction was characterized and a surprising effect of macrocycle halogenation was uncovered.

Operando Characterization of an Amorphous Molybdenum Sulfide Nanoparticle Catalyst during the Hydrogen Evolution Reaction

2014 ◽  
Vol 118 (50) ◽  
pp. 29252-29259 ◽  
Author(s):  
Hernan G. Sanchez Casalongue ◽  
Jesse D. Benck ◽  
Charlie Tsai ◽  
Rasmus K. B. Karlsson ◽  
Sarp Kaya ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Molybdenum Sulfide ◽  
Nanoparticle Catalyst
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