The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

2014 ◽  
Vol 43 (3) ◽  
pp. 945-949 ◽  
Author(s):  
Daopeng Zhang ◽  
Yongzhong Bian ◽  
Jie Qin ◽  
Ping Wang ◽  
Xia Chen
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Antiferromagnetic Coupling ◽  
Supramolecular Interaction ◽  
Single Chain ◽  
One Dimensional ◽  
Chain Complexes

Two cyanide-bridged enantiopure one-dimensional single chain complexes have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the Mn(iii)–Fe(iii) centers and the metamagnetic behavior at about 5.0 K.

scholarly journals Synthesis, Crystal Structure and Magnetic Properties of 1D Chain Complexes Based on Azo Carboxylate Oxime Ligand

2021 ◽  
Vol 7 (7) ◽  
pp. 105
Author(s):  
Min Zeng ◽  
Xi Chen ◽  
Hui-Zhong Kou
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
High Spin ◽  
Magnetic Measurements ◽  
Antiferromagnetic Coupling ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Chain Complexes ◽  
1D Chain ◽  
Oxime Ligand

Two carboxylate-bridged one-dimensional chain complexes, {[MnII(MeOH)2][FeIII(L)2]2}n (1) and {[MnII(DMF)2][MnIII(L)2]2·DMF}n (2) [H2L = ((2-carboxyphenyl)azo)-benzaldoxime], containing a low-spin [FeIII(L)2]− or [MnIII(L)2]− unit were synthesized. Magnetic measurements show that the adjacent high-spin MnII and low-spin MIII ions display weak antiferromagnetic coupling via the syn–anti carboxyl bridges, with J = −0.066(2) cm−1 for complex 1 and J = −0.274(2) cm−1 for complex 2.

Ligand-directed assembly of trinuclear and one-dimensional heterotrimetallic CuIILnIIIFeIIIcomplexes: unusual antiferromagnetic CuIIFeIIIcoupling via cyano bridges

2016 ◽  
Vol 40 (10) ◽  
pp. 8643-8649 ◽  
Author(s):  
Mei-Jiao Liu ◽  
Kong-Qiu Hu ◽  
Cai-Ming Liu ◽  
Ai-Li Cui ◽  
Hui-Zhong Kou
Keyword(s):  
Magnetic Properties ◽  
Directed Assembly ◽  
Antiferromagnetic Coupling ◽  
Single Chain ◽  
One Dimensional ◽  
Trinuclear Complexes

Rare phenoxo- and cyano-bridged CuLnFe trinuclear complexes were prepared. The 1D Cu2DyFe complex displays both single-chain magnetic properties and the intrachain Cu(ii)–Fe(iii) antiferromagnetic coupling.

Rational Design and Assembly of a New Series of Cyanide-Bridged FeIII−MnIIOne-Dimensional Single Chain Complexes: Synthesis, Crystal Structures, and Magnetic Properties

2009 ◽  
Vol 48 (12) ◽  
pp. 5488-5496 ◽  
Author(s):  
Daopeng Zhang ◽  
Hailong Wang ◽  
Yuting Chen ◽  
Zhong-Hai Ni ◽  
Laijin Tian ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Rational Design ◽  
Single Chain ◽  
Chain Complexes

Copper(II) coordination chain complexes with the 3,5-diacetyl-4-methylpyrazole dioxime ligand: Synthesis, crystal structures and magnetic properties

2011 ◽  
Vol 989 (1-3) ◽  
pp. 60-69 ◽  
Author(s):  
Moha Outirite ◽  
Bouchaib Mernari ◽  
Fouad Bentiss ◽  
Frederic Capet ◽  
Michel Lagrenée
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Chain Complexes ◽  
Ligand Synthesis
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