scholarly journals Determination of oxygen adsorption–desorption rates and diffusion rate coefficients in perovskites at different oxygen partial pressures by a microkinetic approach

2015 ◽  
Vol 17 (2) ◽  
pp. 1469-1481 ◽  
Author(s):  
M. Rochoux ◽  
Y. Guo ◽  
Y. Schuurman ◽  
D. Farrusseng

We show a generic method for the measurement of oxygen surface exchange and diffusion parameters from powders allowing the prediction of oxygen flux in membrane configuration.

2019 ◽  
Vol 21 (44) ◽  
pp. 24740-24748 ◽  
Author(s):  
Anna S. Tolkacheva ◽  
Sergey N. Shkerin ◽  
Natalia M. Porotnikova ◽  
Mikhail V. Kuznetsov ◽  
Sergey V. Naumov ◽  
...  

Oxygen surface exchange and diffusion in Ca12Al14O33±δ single crystal were studied by a unique in situ method based on isotope equilibration in the gas phase.


2016 ◽  
Vol 311 (2) ◽  
pp. 1111-1116 ◽  
Author(s):  
Yu-Hung Shih ◽  
Tsuey-Lin Tsai ◽  
Liang-Cheng Chen ◽  
Te-Yen Su ◽  
Chuan-Pin Lee ◽  
...  

2019 ◽  
Vol 21 (9) ◽  
pp. 4779-4790 ◽  
Author(s):  
Evgeniy Tropin ◽  
Maxim Ananyev ◽  
Natalia Porotnikova ◽  
Anna Khodimchuk ◽  
Saim Saher ◽  
...  

Oxygen surface exchange and diffusion in Pr1.75Sr0.25Ni0.75Co0.25O4±δ have been investigated using two methods: pulsed isotope exchange (PIE) and oxygen isotope exchange with gas phase equilibration (IE GPE).


1986 ◽  
Vol 18-19 ◽  
pp. 1038-1044 ◽  
Author(s):  
B STEELE ◽  
J KILNER ◽  
P DENNIS ◽  
A MCHALE ◽  
M VANHEMERT ◽  
...  

2016 ◽  
Vol 18 (13) ◽  
pp. 9102-9111 ◽  
Author(s):  
M. V. Ananyev ◽  
E. S. Tropin ◽  
V. A. Eremin ◽  
A. S. Farlenkov ◽  
A. S. Smirnov ◽  
...  

Oxygen surface exchange kinetics and diffusion have been studied by the isotope exchange method with gas phase equilibration using a static circulation experimental rig in the temperature range of 600–800 °C and oxygen pressure range of 0.13–2.5 kPa.


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