scholarly journals Selective conversion of alcohols in water to carboxylic acids by in situ generated ruthenium trans dihydrido carbonyl PNP complexes

2014 ◽  
Vol 43 (46) ◽  
pp. 17248-17254 ◽  
Author(s):  
Jong-Hoo Choi ◽  
Leo E. Heim ◽  
Mike Ahrens ◽  
Martin H. G. Prechtl
Keyword(s):  
Carboxylic Acids ◽  
Direct Conversion ◽  
Primary Alcohols ◽  
Selective Conversion ◽  
Conversion Of Alcohols

In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source.

ChemInform Abstract: Superoxide (O2-.)-Initiated Oxidation of Primary Alcohols to Carboxylic Acids.

ChemInform ◽  
2010 ◽  
Vol 22 (44) ◽  
pp. no-no
Author(s):  
M. SINGH ◽  
K. N. SINGH ◽  
S. DWIVEDI ◽  
R. A. MISRA
Keyword(s):  
Carboxylic Acids ◽  
Primary Alcohols

An Improved and Practical Sharpless Oxidation of Primary Alcohols to the Carboxylic Acids

1999 ◽  
Vol 29 (17) ◽  
pp. 2937-2942 ◽  
Author(s):  
Mahavir Prashad ◽  
Yansong Lu ◽  
Hong-Yong Kim ◽  
Bin Hu ◽  
Oljan Repic ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Primary Alcohols

scholarly journals Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

2020 ◽  
Author(s):  
Anna Davies ◽  
keegan fitzpatrick ◽  
Rick Betori ◽  
Karl Scheidt
Keyword(s):  
Carboxylic Acids ◽  
Late Stage ◽  
Pharmaceutical Compounds ◽  
Single Electron ◽  
Photoredox Catalysis ◽  
Radical Coupling ◽  
Electron Reduction

Disclosed herein is the development of a novel single-electron reduction of acyl azoliums for the formation of ketones from carboxylic acids. Facile construction of the acyl azolium <i>in situ</i> followed by a radical-radical coupling was made possible using merged NHC-photoredox catalysis. The utility of this protocol in synthesis was demonstrated in the late-stage functionalization of a variety of pharmaceutical compounds.

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