ruthenium hydride
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Dehydrogenative alcohol coupling and one-pot cross metathesis/dehydrogenative coupling reactions of alcohols using Hoveyda-Grubbs catalysts

2021 ◽  
Author(s):  
Halenur Özer ◽  
Dilan Arslan ◽  
Bengi Öztürk
Keyword(s):  
Coupling Reactions ◽  
One Pot ◽  
Ruthenium Hydride ◽  
Cross Metathesis ◽  
Dehydrogenative Coupling ◽  
Grubbs Catalysts

In this study, in-situ formed ruthenium hydride species that were generated from Grubbs type catalyst are used as efficient catalysts for dehydrogenative alcohol coupling and sequential cross-metathesis/dehydrogenative coupling reactions. The...

Ruthenium‐Hydride Assisted Remarkable Diversity Towards Non‐Spectator Feature of Benzodifuroxan

2020 ◽  
Vol 15 (20) ◽  
pp. 3281-3295
Author(s):  
Sanchaita Dey ◽  
Sanjib Panda ◽  
Goutam Kumar Lahiri
Keyword(s):  
Ruthenium Hydride

scholarly journals Mechanism of the Facile Nitrous Oxide Fixation by Homogeneous Ruthenium Hydride Pincer Catalysts

2020 ◽  
Vol 59 (13) ◽  
pp. 9374-9383
Author(s):  
Sílvia Escayola ◽  
Miquel Solà ◽  
Albert Poater
Keyword(s):  
Nitrous Oxide ◽  
Ruthenium Hydride

scholarly journals Effects of ruthenium hydride species on primary amine synthesis by direct amination of alcohols over a heterogeneous Ru catalyst

2020 ◽  
Vol 11 (36) ◽  
pp. 9884-9890 ◽  
Author(s):  
Yusuke Kita ◽  
Midori Kuwabara ◽  
Satoshi Yamadera ◽  
Keigo Kamata ◽  
Michikazu Hara
Keyword(s):  
Primary Amine ◽  
Catalytic Performance ◽  
Direct Amination ◽  
Ruthenium Hydride ◽  
Ru Catalyst

Ru–MgO/TiO2 exhibited high catalytic performance for direct amination of alcohols based on the acceleration effects of MgO.

Geometric isomerization and geometry controlled catalytic alcohol aminations of ruthenium hydride compounds containing bidentate pyrrolyl-imines

2019 ◽  
Vol 902 ◽  
pp. 120957
Author(s):  
Yong-Jie Li ◽  
Hsuan-Ting Lai ◽  
Ching-Han Hu ◽  
Jie-Hong Chen ◽  
Chia-Her Lin ◽  
...  
Keyword(s):  
Ruthenium Hydride ◽  
Geometric Isomerization

Thermal isomerization of ruthenium hydride compounds containing asymmetric bidentate pyrrole‐imine ligands

2019 ◽  
Vol 66 (9) ◽  
pp. 1041-1047
Author(s):  
Hsuan‐Ting Lai ◽  
Kun‐Hao Chen ◽  
Yong‐Jie Li ◽  
Cheng‐Hsien Wu ◽  
Ching‐Han Hu ◽  
...  
Keyword(s):  
Thermal Isomerization ◽  
Ruthenium Hydride ◽  
Imine Ligands

scholarly journals Synthesis of Dihydropyrano[3,2-c]pyrazoles via Double Bond Migration and Ring-Closing Metathesis

Molecules ◽  
2019 ◽  
Vol 24 (2) ◽  
pp. 296 ◽  
Author(s):  
Yoshihide Usami ◽  
Kodai Sumimoto ◽  
Azusa Kishima ◽  
Yuya Tatsui ◽  
Hiroki Yoneyama ◽  
...  
Keyword(s):  
Double Bond ◽  
Claisen Rearrangement ◽  
Ring Closing Metathesis ◽  
Double Bond Migration ◽  
Ruthenium Hydride

Three types of pyrazole-fused heterobicycles, i.e., 1,5-, 1,7-, and 2,5-dihydropyrano[3,2-c]pyrazoles, were synthesized from 4-allyloxy-1H-pyrazoles. A sequence of the Claisen rearrangement of 4-allyloxy-1H-pyrazoles, ruthenium-hydride-catalyzed double bond migration, O-allylation, and ring-closing metathesis was employed in this study.

scholarly journals Heterobimetallic ruthenium–zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity

2019 ◽  
Vol 48 (13) ◽  
pp. 4176-4189 ◽  
Author(s):  
Maialen Espinal-Viguri ◽  
Victor Varela-Izquierdo ◽  
Fedor M. Miloserdov ◽  
Ian M. Riddlestone ◽  
Mary F. Mahon ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Zinc Complexes ◽  
Ruthenium Hydride ◽  
Hydride Complexes ◽  
Heterobimetallic Complexes ◽  
P Addition

Addition of ZnMe2 to cationic and neutral ruthenium hydride complexes bearing NHC ligands affords new Ru–Zn heterobimetallic complexes.

Phosphine-free ruthenium NCN-ligand complexes and their use in catalytic CO2 hydrogenation

2019 ◽  
Vol 48 (44) ◽  
pp. 16569-16577
Author(s):  
Molly M. H. Sung ◽  
Demyan E. Prokopchuk ◽  
Robert H. Morris
Keyword(s):  
Carbon Dioxide ◽  
Co2 Hydrogenation ◽  
Ruthenium Hydride ◽  
Hydrogenation Of Carbon Dioxide

A ruthenium hydride with a fluxional NHC ligand catalyses the hydrogenation of carbon dioxide.

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