Triazolate-based 3D frameworks and a 2D layer with centrosymmetric CuII7, CuII5, CuII4 clusters and tunable interlayer/interchain compactness: hydrothermal syntheses, crystal structures and magnetic properties

2015 ◽  
Vol 44 (12) ◽  
pp. 5826-5836 ◽  
Author(s):  
Yuan-Yuan Zhang ◽  
Hong Zhao ◽  
En-Cui Yang ◽  
Zhong-Yi Liu ◽  
Qiu Shang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Ground States ◽  
Hydrothermal Syntheses

A 2D layer and three 3D frameworks with different interchain/interlayer compactness and spin ground-states were reported.

Hydrothermal syntheses, structural characterizations, and magnetic properties of five MOFs assembled from C2-symmetric ligand of 1,3-di(2′,4′-dicarboxylphenyl)benzene with various coordination modes

RSC Advances ◽  
2015 ◽  
Vol 5 (50) ◽  
pp. 39854-39863 ◽  
Author(s):  
Liming Fan ◽  
Weiliu Fan ◽  
Bin Li ◽  
Xian Zhao ◽  
Xiutang Zhang
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Structural Features ◽  
Paddle Wheel ◽  
Coordination Modes ◽  
Hydrothermal Syntheses ◽  
Structural Characterizations

Five new complexes with appealing structural features from 0D paddle wheel {Cu2(COO)4} SBUs to 3D frameworks were reported to better understand the synthon selectivity in multifunctional crystal structures.

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